Controlling embedment and surface chemistry of nanoclusters in metal-organic frameworks

D. E. Coupry; J. Butson; P. S. Petkov; M. Saunders; K. O'Donnell; H. Kim; C. Buckley; M. Addicoat; T. Heine; P. A. Szilagyi

doi:10.1039/c6cc00659k

Controlling embedment and surface chemistry of nanoclusters in metal-organic frameworks

D. E. Coupry
, J. Butson
, P. S. Petkov
, M. Saunders
, K. O'Donnell
, H. Kim
, C. Buckley
, M. Addicoat
, T. Heine
, P. A. Szilagyi

Centre for Microscopy, Characterisation & Analysis

Research output: Contribution to journal › Article › peer-review

21 Citations (Web of Science)

Abstract

A combined theoretical and experimental approach demonstrates that nanocluster embedment into the pores of metal-organic frameworks (MOF) may be influenced by the chemical functionalisation of the MOF. Furthermore, this results in the surface functionalisation of the embedded nanoclusters, highlighting the potential of MOF scaffolds for the design and synthesis of novel functional materials.

Original language	English
Pages (from-to)	5175-5178
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	29
Early online date	15 Mar 2016
DOIs	https://doi.org/10.1039/c6cc00659k
Publication status	Published - 14 Apr 2016

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10.1039/c6cc00659kLicence: CC BY

A State of the Art Surface Characterisation Facility
Buckley, C. (Investigator 01), Raston, C. (Investigator 02), Hinckley, S. (Investigator 03) & De Marco, R. (Investigator 04)
ARC Australian Research Council
1/01/12 → 31/12/12
Project: Research

Cite this

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abstract = "A combined theoretical and experimental approach demonstrates that nanocluster embedment into the pores of metal-organic frameworks (MOF) may be influenced by the chemical functionalisation of the MOF. Furthermore, this results in the surface functionalisation of the embedded nanoclusters, highlighting the potential of MOF scaffolds for the design and synthesis of novel functional materials.",

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AU - Coupry, D. E.

AU - Butson, J.

AU - Petkov, P. S.

AU - Saunders, M.

AU - O'Donnell, K.

AU - Kim, H.

AU - Buckley, C.

AU - Addicoat, M.

AU - Heine, T.

AU - Szilagyi, P. A.

PY - 2016/4/14

Y1 - 2016/4/14

N2 - A combined theoretical and experimental approach demonstrates that nanocluster embedment into the pores of metal-organic frameworks (MOF) may be influenced by the chemical functionalisation of the MOF. Furthermore, this results in the surface functionalisation of the embedded nanoclusters, highlighting the potential of MOF scaffolds for the design and synthesis of novel functional materials.

AB - A combined theoretical and experimental approach demonstrates that nanocluster embedment into the pores of metal-organic frameworks (MOF) may be influenced by the chemical functionalisation of the MOF. Furthermore, this results in the surface functionalisation of the embedded nanoclusters, highlighting the potential of MOF scaffolds for the design and synthesis of novel functional materials.

KW - DENSITY-FUNCTIONAL THEORY

KW - SELECTIVE OXIDATION

KW - HETEROGENEOUS CATALYSIS

KW - ACCURATE DESCRIPTION

KW - HYDROGEN SPILLOVER

KW - CLUSTERS

KW - NANOPARTICLES

KW - LUMINESCENT

KW - IRIDIUM

KW - RHODIUM

U2 - 10.1039/c6cc00659k

DO - 10.1039/c6cc00659k

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VL - 52

SP - 5175

EP - 5178

JO - Chemical Communications

JF - Chemical Communications

IS - 29

ER -

Controlling embedment and surface chemistry of nanoclusters in metal-organic frameworks

Abstract

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A State of the Art Surface Characterisation Facility

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