Complex Salts Derived from the Reactions of Organotin(IV) with 6-Methylpyridine-2-Carboxaldehyde Phenylhydrazone : X-Ray Crystal Structure of Bis 6-Methylpyridine-2-Carboxaldehydehydrazodium-Tetrachlorodimethylstannate(IV)

S-B. Teo; L-M. Yeow; G-Y. Yeap; N. Ishizawa; B. Etschmann; Brian Skelton

doi:10.1080/0095897031000069012

Complex Salts Derived from the Reactions of Organotin(IV) with 6-Methylpyridine-2-Carboxaldehyde Phenylhydrazone : X-Ray Crystal Structure of Bis 6-Methylpyridine-2-Carboxaldehydehydrazodium-Tetrachlorodimethylstannate(IV)

S-B. Teo, L-M. Yeow, G-Y. Yeap, N. Ishizawa, B. Etschmann, Brian Skelton

Centre for Microscopy, Characterisation & Analysis

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Reactions of organotin(IV) chloride (Me2SnCl2, PhSnCl3 and n-BuSnCl3) with the Schiff base 6-methylpyridine-2-carboxaldehyde phenylhydrazone (L) result in the formation of organotin(IV) anionic complexes. Me2SnCl2 reacts with L in dichloromethane to form [LH+](2)[Me2SnCl4](2-). X-ray structural analysis has been carried out on the complex salt bis[6-methylpyridine-2-carboxaldehydehydrazodium]tetrachlorodimethylstannate(IV), [LH+](2)[Me2SnCl4](2-) wherein the tin moieties exist as monomers. Reactions of PhSnCl3 and n-BuSnCl3 with L form the complexes [LH+](2)[PhSnCl5](2-) and [LH+](2)[n-BuSnCl5](2-). Compounds were also characterized by FTIR, H-1 and C-13 NMR spectroscopy.

Original language	English
Pages (from-to)	215-221
Journal	Journal of Coordination Chemistry
Volume	56
Issue number	3
DOIs	https://doi.org/10.1080/0095897031000069012
Publication status	Published - 2003

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Teo, S.-B., Yeow, L.-M., Yeap, G.-Y., Ishizawa, N., Etschmann, B., & Skelton, B. (2003). Complex Salts Derived from the Reactions of Organotin(IV) with 6-Methylpyridine-2-Carboxaldehyde Phenylhydrazone : X-Ray Crystal Structure of Bis 6-Methylpyridine-2-Carboxaldehydehydrazodium-Tetrachlorodimethylstannate(IV). Journal of Coordination Chemistry, 56(3), 215-221. https://doi.org/10.1080/0095897031000069012

@article{529b8068fcec406eb3909ffe36321cce,

title = "Complex Salts Derived from the Reactions of Organotin(IV) with 6-Methylpyridine-2-Carboxaldehyde Phenylhydrazone : X-Ray Crystal Structure of Bis 6-Methylpyridine-2-Carboxaldehydehydrazodium-Tetrachlorodimethylstannate(IV)",

abstract = "Reactions of organotin(IV) chloride (Me2SnCl2, PhSnCl3 and n-BuSnCl3) with the Schiff base 6-methylpyridine-2-carboxaldehyde phenylhydrazone (L) result in the formation of organotin(IV) anionic complexes. Me2SnCl2 reacts with L in dichloromethane to form [LH+](2)[Me2SnCl4](2-). X-ray structural analysis has been carried out on the complex salt bis[6-methylpyridine-2-carboxaldehydehydrazodium]tetrachlorodimethylstannate(IV), [LH+](2)[Me2SnCl4](2-) wherein the tin moieties exist as monomers. Reactions of PhSnCl3 and n-BuSnCl3 with L form the complexes [LH+](2)[PhSnCl5](2-) and [LH+](2)[n-BuSnCl5](2-). Compounds were also characterized by FTIR, H-1 and C-13 NMR spectroscopy.",

author = "S-B. Teo and L-M. Yeow and G-Y. Yeap and N. Ishizawa and B. Etschmann and Brian Skelton",

year = "2003",

doi = "10.1080/0095897031000069012",

language = "English",

volume = "56",

pages = "215--221",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor & Francis",

number = "3",

}

Teo, S-B, Yeow, L-M, Yeap, G-Y, Ishizawa, N, Etschmann, B & Skelton, B 2003, 'Complex Salts Derived from the Reactions of Organotin(IV) with 6-Methylpyridine-2-Carboxaldehyde Phenylhydrazone : X-Ray Crystal Structure of Bis 6-Methylpyridine-2-Carboxaldehydehydrazodium-Tetrachlorodimethylstannate(IV)', Journal of Coordination Chemistry, vol. 56, no. 3, pp. 215-221. https://doi.org/10.1080/0095897031000069012

Complex Salts Derived from the Reactions of Organotin(IV) with 6-Methylpyridine-2-Carboxaldehyde Phenylhydrazone : X-Ray Crystal Structure of Bis 6-Methylpyridine-2-Carboxaldehydehydrazodium-Tetrachlorodimethylstannate(IV). / Teo, S-B.; Yeow, L-M.; Yeap, G-Y. et al.
In: Journal of Coordination Chemistry, Vol. 56, No. 3, 2003, p. 215-221.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Complex Salts Derived from the Reactions of Organotin(IV) with 6-Methylpyridine-2-Carboxaldehyde Phenylhydrazone : X-Ray Crystal Structure of Bis 6-Methylpyridine-2-Carboxaldehydehydrazodium-Tetrachlorodimethylstannate(IV)

AU - Teo, S-B.

AU - Yeow, L-M.

AU - Yeap, G-Y.

AU - Ishizawa, N.

AU - Etschmann, B.

AU - Skelton, Brian

PY - 2003

Y1 - 2003

N2 - Reactions of organotin(IV) chloride (Me2SnCl2, PhSnCl3 and n-BuSnCl3) with the Schiff base 6-methylpyridine-2-carboxaldehyde phenylhydrazone (L) result in the formation of organotin(IV) anionic complexes. Me2SnCl2 reacts with L in dichloromethane to form [LH+](2)[Me2SnCl4](2-). X-ray structural analysis has been carried out on the complex salt bis[6-methylpyridine-2-carboxaldehydehydrazodium]tetrachlorodimethylstannate(IV), [LH+](2)[Me2SnCl4](2-) wherein the tin moieties exist as monomers. Reactions of PhSnCl3 and n-BuSnCl3 with L form the complexes [LH+](2)[PhSnCl5](2-) and [LH+](2)[n-BuSnCl5](2-). Compounds were also characterized by FTIR, H-1 and C-13 NMR spectroscopy.

AB - Reactions of organotin(IV) chloride (Me2SnCl2, PhSnCl3 and n-BuSnCl3) with the Schiff base 6-methylpyridine-2-carboxaldehyde phenylhydrazone (L) result in the formation of organotin(IV) anionic complexes. Me2SnCl2 reacts with L in dichloromethane to form [LH+](2)[Me2SnCl4](2-). X-ray structural analysis has been carried out on the complex salt bis[6-methylpyridine-2-carboxaldehydehydrazodium]tetrachlorodimethylstannate(IV), [LH+](2)[Me2SnCl4](2-) wherein the tin moieties exist as monomers. Reactions of PhSnCl3 and n-BuSnCl3 with L form the complexes [LH+](2)[PhSnCl5](2-) and [LH+](2)[n-BuSnCl5](2-). Compounds were also characterized by FTIR, H-1 and C-13 NMR spectroscopy.

U2 - 10.1080/0095897031000069012

DO - 10.1080/0095897031000069012

M3 - Article

SN - 0095-8972

VL - 56

SP - 215

EP - 221

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 3

ER -

Teo SB, Yeow LM, Yeap GY, Ishizawa N, Etschmann B, Skelton B. Complex Salts Derived from the Reactions of Organotin(IV) with 6-Methylpyridine-2-Carboxaldehyde Phenylhydrazone : X-Ray Crystal Structure of Bis 6-Methylpyridine-2-Carboxaldehydehydrazodium-Tetrachlorodimethylstannate(IV). Journal of Coordination Chemistry. 2003;56(3):215-221. doi: 10.1080/0095897031000069012