Competition between cluster fragmentation, C-C bond coupling and C-X bond activation in silver hexynyl cluster cations, [(C4H9CCAg)(n)Ag](+). Size does matter!

F.Q. Wang; G.N. Khairallah; George Koutsantonis; C.M. Williams; D.L. Callahan; R.A.J. O'Hair

doi:10.1039/b904687a

Competition between cluster fragmentation, C-C bond coupling and C-X bond activation in silver hexynyl cluster cations, [(C4H9CCAg)(n)Ag](+). Size does matter!

F.Q. Wang, G.N. Khairallah, George Koutsantonis, C.M. Williams, D.L. Callahan, R.A.J. O'Hair

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Silverhexynylcluster cations, [(C4H9CCAg)nAg]+, exhibit a rich unimolecular chemistry that is dependant on the cluster size, n (1–5), cluster fragmentation (for all n > 1); C–C bond coupling (n = 3 & 4); C–H bond activation with comcomitant silver hydride formation (n = 1 & 4); C–C bond activation (n = 1 & 4).

Original language	English
Pages (from-to)	4132-4135
Journal	Physical Chemistry Chemical Physics
Volume	11
Issue number	21
DOIs	https://doi.org/10.1039/b904687a
Publication status	Published - 2009

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title = "Competition between cluster fragmentation, C-C bond coupling and C-X bond activation in silver hexynyl cluster cations, [(C4H9CCAg)(n)Ag](+). Size does matter!",

abstract = "Silverhexynylcluster cations, [(C4H9CCAg)nAg]+, exhibit a rich unimolecular chemistry that is dependant on the cluster size, n (1–5), cluster fragmentation (for all n > 1); C–C bond coupling (n = 3 & 4); C–H bond activation with comcomitant silver hydride formation (n = 1 & 4); C–C bond activation (n = 1 & 4).",

author = "F.Q. Wang and G.N. Khairallah and George Koutsantonis and C.M. Williams and D.L. Callahan and R.A.J. O'Hair",

year = "2009",

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T1 - Competition between cluster fragmentation, C-C bond coupling and C-X bond activation in silver hexynyl cluster cations, [(C4H9CCAg)(n)Ag](+). Size does matter!

AU - Wang, F.Q.

AU - Khairallah, G.N.

AU - Koutsantonis, George

AU - Williams, C.M.

AU - Callahan, D.L.

AU - O'Hair, R.A.J.

PY - 2009

Y1 - 2009

N2 - Silverhexynylcluster cations, [(C4H9CCAg)nAg]+, exhibit a rich unimolecular chemistry that is dependant on the cluster size, n (1–5), cluster fragmentation (for all n > 1); C–C bond coupling (n = 3 & 4); C–H bond activation with comcomitant silver hydride formation (n = 1 & 4); C–C bond activation (n = 1 & 4).

AB - Silverhexynylcluster cations, [(C4H9CCAg)nAg]+, exhibit a rich unimolecular chemistry that is dependant on the cluster size, n (1–5), cluster fragmentation (for all n > 1); C–C bond coupling (n = 3 & 4); C–H bond activation with comcomitant silver hydride formation (n = 1 & 4); C–C bond activation (n = 1 & 4).

U2 - 10.1039/b904687a

DO - 10.1039/b904687a

M3 - Article

C2 - 19458814

SN - 1463-9076

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SP - 4132

EP - 4135

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 21

ER -

Competition between cluster fragmentation, C-C bond coupling and C-X bond activation in silver hexynyl cluster cations, [(C4H9CCAg)(n)Ag](+). Size does matter!

Abstract

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