Chloro(phenyl)(1H-pyrazole-kN)-(triphenylphosphine-kP) palladium(II)

A.J. Canty, Brian Skelton, Allan White

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

In the title compound, [Pd(C6H5)Cl(C3H4N2){P(C6H5)3}], the phenyl and Cl ligands lie mutually trans. The compound is the first structurally characterized complex with four monodentate Cl, P, N and (non-carbenoid) C ligands in a square-planar four-coordinate palladium(II) environment. The pyrazole ligand is coplanar with the latter array. The pyrazole NH group forms a bifurcated hydrogen bond to Cl, with an intra- and intermolecular component.
Original languageEnglish
Pages (from-to)M405-M406
JournalActa Crystallographica Section C: Structural Chemistry
VolumeC60
Issue number8
DOIs
Publication statusPublished - 2004

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