Chlorido[1-diphenylphosphanyl-3-(phenylsulfanyl)propane-kappa P-2,S](eta(5)-pentamethylcyclopentadienyl)iridium(III) chloride monohydrate

Gerd Ludwig, Marcus Korb, Tobias Rueffer, Heinrich Lang, Dirk Steinborn

Research output: Contribution to journalArticle

Abstract

The crystal structure of the title compound, [Ir(C10H15)Cl(C21H21PS)]Cl center dot H2O, consists of discrete [Ir(eta(5)-C5Me5)Cl{Ph2P(CH2)(3)SPh-kappa P,kappa S}](+) cations, chloride anions and water molecules. The Ir-III atom is coordinated by an eta(5)-C5Me5 ligand, a chloride and a Ph2P(CH2)(3)SPh-kappa P,kappa S ligand, leading to a three-legged piano-stool geometry. In the crystal, two water molecules and two chloride anions are linked by weak O-H center dot center dot center dot Cl hydrogen bonding into tetramers that are located on centers of inversion. The H atoms of one of the methyl groups are disordered and were refined using a split model.

Original languageEnglish
Pages (from-to)M858-+
Number of pages12
JournalActa Crystallographica. Section E: Structure Reports Online
Volume68
DOIs
Publication statusPublished - Jun 2012
Externally publishedYes

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