TY - JOUR
T1 - Chloride and phosphide-substituted gallium hydrides
T2 - [Cy 3PGaH3-nCln] n=1 or 2, and trimeric [{H 2Ga(μ-PCy2)}3]
AU - Elms, F. M.
AU - Koutsantonis, G. A.
AU - Raston, C. L.
PY - 1995/12/1
Y1 - 1995/12/1
N2 - Thermally robust chlorogallanes, Cy3PGaH2Cl 1 and Cy3PGaHCl2 2, accessible by redistribution reactions involving Cy3PGaH3 and Cy3PGaCl3 (Cy=cyclohexyl) or 1 via anhydrous HCl reaction with Cy3PGaH 3, show phosphine but not chloride-hydride exchange in aromatic solvents; treatment of 1 with [Li(PCy2)(thf)n] affords trimeric [{H2Ga(μ-PCy2)}3] 3, which crystallises in a twist-boat conformation.
AB - Thermally robust chlorogallanes, Cy3PGaH2Cl 1 and Cy3PGaHCl2 2, accessible by redistribution reactions involving Cy3PGaH3 and Cy3PGaCl3 (Cy=cyclohexyl) or 1 via anhydrous HCl reaction with Cy3PGaH 3, show phosphine but not chloride-hydride exchange in aromatic solvents; treatment of 1 with [Li(PCy2)(thf)n] affords trimeric [{H2Ga(μ-PCy2)}3] 3, which crystallises in a twist-boat conformation.
UR - http://www.scopus.com/inward/record.url?scp=37049066769&partnerID=8YFLogxK
U2 - 10.1039/C39950001669
DO - 10.1039/C39950001669
M3 - Article
AN - SCOPUS:37049066769
SN - 0022-4936
SP - 1669
EP - 1670
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 16
ER -