Chirality and Encapsulation Properties of Disubstituted Ferrocene - Peptide Dendrimers

F.E. Appoh; Donald Thomas; H.B. Kraatz

doi:10.1021/ma060525x

Chirality and Encapsulation Properties of Disubstituted Ferrocene - Peptide Dendrimers

F.E. Appoh, Donald Thomas, H.B. Kraatz

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The synthesis and spectroscopic characterization of novel disubstituted glutamic acid dendrimers constructed on a ferrocene core are reported. The strong intramolecular hydrogen bonding observed in monosubstituted variants of the currently studied dendrimers is also observed for the disubstituted systems. DMSO is found to selectively disrupt this hydrogen bonding. The absence of any redox activity in generations 5 and 6 demonstrates the complete encapsulation of the ferrocene core.

Original language	English
Pages (from-to)	5629-5638
Journal	Macromolecules
Volume	39
DOIs	https://doi.org/10.1021/ma060525x
Publication status	Published - 2006

Access to Document

10.1021/ma060525x

Cite this

@article{afd7e3836341410f8aecddc70977a53c,

title = "Chirality and Encapsulation Properties of Disubstituted Ferrocene - Peptide Dendrimers",

abstract = "The synthesis and spectroscopic characterization of novel disubstituted glutamic acid dendrimers constructed on a ferrocene core are reported. The strong intramolecular hydrogen bonding observed in monosubstituted variants of the currently studied dendrimers is also observed for the disubstituted systems. DMSO is found to selectively disrupt this hydrogen bonding. The absence of any redox activity in generations 5 and 6 demonstrates the complete encapsulation of the ferrocene core.",

author = "F.E. Appoh and Donald Thomas and H.B. Kraatz",

year = "2006",

doi = "10.1021/ma060525x",

language = "English",

volume = "39",

pages = "5629--5638",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

}

TY - JOUR

T1 - Chirality and Encapsulation Properties of Disubstituted Ferrocene - Peptide Dendrimers

AU - Appoh, F.E.

AU - Thomas, Donald

AU - Kraatz, H.B.

PY - 2006

Y1 - 2006

N2 - The synthesis and spectroscopic characterization of novel disubstituted glutamic acid dendrimers constructed on a ferrocene core are reported. The strong intramolecular hydrogen bonding observed in monosubstituted variants of the currently studied dendrimers is also observed for the disubstituted systems. DMSO is found to selectively disrupt this hydrogen bonding. The absence of any redox activity in generations 5 and 6 demonstrates the complete encapsulation of the ferrocene core.

AB - The synthesis and spectroscopic characterization of novel disubstituted glutamic acid dendrimers constructed on a ferrocene core are reported. The strong intramolecular hydrogen bonding observed in monosubstituted variants of the currently studied dendrimers is also observed for the disubstituted systems. DMSO is found to selectively disrupt this hydrogen bonding. The absence of any redox activity in generations 5 and 6 demonstrates the complete encapsulation of the ferrocene core.

U2 - 10.1021/ma060525x

DO - 10.1021/ma060525x

M3 - Article

SN - 0024-9297

VL - 39

SP - 5629

EP - 5638

JO - Macromolecules

JF - Macromolecules

ER -

Chirality and Encapsulation Properties of Disubstituted Ferrocene - Peptide Dendrimers

Abstract

Access to Document

Fingerprint

Cite this