TY - JOUR
T1 - Chemical erosion by deuterium impact on carbon films doped with nanometer-sized carbide crystallites
AU - Balden, M.
AU - Adelhelm, C.
AU - de Juan Pardo, E.
AU - Roth, J.
PY - 2007/6/15
Y1 - 2007/6/15
N2 - The erosion by 30 and 200 eV/D at temperatures between 300 and 1100 K was investigated for magnetron-sputtered films, consisting of carbon and metal (2-7 at.% W, Ti, Zr) present as nanometer-sized carbide crystallites. The total erosion yield was determined from weight-loss measurements and film thickness changes measured by RBS. The chemical erosion yield was obtained from the CD4 signal of mass spectrometry. The total erosion yield of doped films is reduced by a factor of 3-20 compared to pure C films. The CD4 production yield decreases less implying that the distribution of the chemically eroded species was changed by the dopants. Therefore, measuring only CD4 production or its spectroscopic signature could yield to misleading values and interpretations.
AB - The erosion by 30 and 200 eV/D at temperatures between 300 and 1100 K was investigated for magnetron-sputtered films, consisting of carbon and metal (2-7 at.% W, Ti, Zr) present as nanometer-sized carbide crystallites. The total erosion yield was determined from weight-loss measurements and film thickness changes measured by RBS. The chemical erosion yield was obtained from the CD4 signal of mass spectrometry. The total erosion yield of doped films is reduced by a factor of 3-20 compared to pure C films. The CD4 production yield decreases less implying that the distribution of the chemically eroded species was changed by the dopants. Therefore, measuring only CD4 production or its spectroscopic signature could yield to misleading values and interpretations.
KW - Amorphous films
KW - Carbon-based materials
KW - Chemical erosion
KW - Erosion and deposition
KW - Hydrocarbons
UR - http://www.scopus.com/inward/record.url?scp=34248545278&partnerID=8YFLogxK
U2 - 10.1016/j.jnucmat.2007.01.188
DO - 10.1016/j.jnucmat.2007.01.188
M3 - Article
AN - SCOPUS:34248545278
SN - 0022-3115
VL - 363-365
SP - 1173
EP - 1178
JO - Journal of Nuclear Materials
JF - Journal of Nuclear Materials
IS - 1-3
ER -