TY - JOUR
T1 - Characterization of a crystalline residue from a swimming pool: disodium copper(II) tetrakis(isocyanurate) hexahydrate
AU - Hart, R.D.
AU - Skelton, Brian
AU - White, Allan
PY - 1992
Y1 - 1992
N2 - Coupled with chemical analysis, a single-crystal X-ray structure determination of lilac deposit from a swimming pool, shows the deposit to be the title compound Na2CU(C3H2N3O3)4.6H2O. Crystals are triclinic, P1BAR, a 10.459(1), b 10.434(3), c 6.762(4) angstrom, alpha 71.73(4), beta 83.67(4), gamma 62.82(2), Z 1 formula unit; 1265 'observed' diffractometer reflections were refined to R 0.052. The copper atoms are located on crystallographic inversion centres, four-coordinated by a pair of water molecules [Cu-O, 1.937(6) angstrom] and a pair of ligand nitrogen atoms [Cu-N, 1.941(9) angstrom]. Interactions from ligand oxygen atoms to sodium ions link the structure into a polymeric array.
AB - Coupled with chemical analysis, a single-crystal X-ray structure determination of lilac deposit from a swimming pool, shows the deposit to be the title compound Na2CU(C3H2N3O3)4.6H2O. Crystals are triclinic, P1BAR, a 10.459(1), b 10.434(3), c 6.762(4) angstrom, alpha 71.73(4), beta 83.67(4), gamma 62.82(2), Z 1 formula unit; 1265 'observed' diffractometer reflections were refined to R 0.052. The copper atoms are located on crystallographic inversion centres, four-coordinated by a pair of water molecules [Cu-O, 1.937(6) angstrom] and a pair of ligand nitrogen atoms [Cu-N, 1.941(9) angstrom]. Interactions from ligand oxygen atoms to sodium ions link the structure into a polymeric array.
M3 - Article
SN - 0004-9425
VL - 45
SP - 1927
EP - 1932
JO - Australian Journal of Chemistry:an international journal for chemical science
JF - Australian Journal of Chemistry:an international journal for chemical science
ER -