Bubbles pinned on electrodes: Friends or foes of aqueous electrochemistry?

Simone Ciampi, K. Swaminathan Iyer

Research output: Contribution to journalReview articlepeer-review

1 Citation (Web of Science)


Electrochemists and engineers regard adherent gas bubbles as redox-inactive and therefore blocking entities. Adhesion of bubbles at electrodes generally carries an energy penalty. But this is not always the case: bubbles pinned on an electrode surface initiate the oxidation of water-soluble species under conditions where such reactions would normally be considered impossible. Here we critically review the recent literature that is beginning to unveil the novel concept of on-water electrochemistry. Harnessing electrochemical reactivity of the water–gas–electrode interface has the potential to become a game-changer in organic electrosynthesis, accelerating the transition toward a sustainable chemical industry by simplifying the direct integration of renewable electricity into the production of commodity chemicals.

Original languageEnglish
Article number100992
JournalCurrent Opinion in Electrochemistry
Publication statusPublished - Aug 2022


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