Bis[tris(1-methyl-1H-imidazol-2-yl)-phosphine-κ3N3]iron(II) tetrachloroferrate(II) methanol tetrasolvate (ca 153 K) and bis[tris(1-methyl-1H-imidazol-2-yl)methanol-κ3N3]iron(III) bis[tetrachloroferrate(III)] chloride (redetermination, ca 153 K)

M.P. Batten; A.J. Canty; K.J. Cavell; T. Ruther; Brian Skelton; Allan White

doi:10.1107/S0108270104010868

Bis[tris(1-methyl-1H-imidazol-2-yl)-phosphine-κ3N3]iron(II) tetrachloroferrate(II) methanol tetrasolvate (ca 153 K) and bis[tris(1-methyl-1H-imidazol-2-yl)methanol-κ3N3]iron(III) bis[tetrachloroferrate(III)] chloride (redetermination, ca 153 K)

M.P. Batten, A.J. Canty, K.J. Cavell, T. Ruther, Brian Skelton, Allan White

Research output: Contribution to journal › Article

10 Citations (Scopus)

Abstract

The first of the title compounds, [Fe(C12H15N6P)2][FeCl4]·4CH4O, is the first homoleptic bis(ligand)iron(II) species reported for this phosphorus bridgehead ligand; interestingly, the complex is isomorphous with its tris(1-methyl-1H-imidazol-2-yl)methanol counterpart, the second of the title compounds, [Fe(C13H16N6O)2][FeCl4]2Cl. In both compounds, the Fe atom of the cation lies on an inversion centre. The structure determinations presented here allow an interesting comparison of iron(II) and iron(III) species in similar coordination environments.

Original language	English
Pages (from-to)	m311-m313
Journal	Acta Crystallographica Section C: Structural Chemistry
Volume	C60
Issue number	7
DOIs	https://doi.org/10.1107/S0108270104010868
Publication status	Published - 2004

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Batten, M. P., Canty, A. J., Cavell, K. J., Ruther, T., Skelton, B., & White, A. (2004). Bis[tris(1-methyl-1H-imidazol-2-yl)-phosphine-κ3N3]iron(II) tetrachloroferrate(II) methanol tetrasolvate (ca 153 K) and bis[tris(1-methyl-1H-imidazol-2-yl)methanol-κ3N3]iron(III) bis[tetrachloroferrate(III)] chloride (redetermination, ca 153 K). Acta Crystallographica Section C: Structural Chemistry, C60(7), m311-m313. https://doi.org/10.1107/S0108270104010868

Batten, M.P. ; Canty, A.J. ; Cavell, K.J. ; Ruther, T. ; Skelton, Brian ; White, Allan. / Bis[tris(1-methyl-1H-imidazol-2-yl)-phosphine-κ3N3]iron(II) tetrachloroferrate(II) methanol tetrasolvate (ca 153 K) and bis[tris(1-methyl-1H-imidazol-2-yl)methanol-κ3N3]iron(III) bis[tetrachloroferrate(III)] chloride (redetermination, ca 153 K). In: Acta Crystallographica Section C: Structural Chemistry. 2004 ; Vol. C60, No. 7. pp. m311-m313.

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title = "Bis[tris(1-methyl-1H-imidazol-2-yl)-phosphine-κ3N3]iron(II) tetrachloroferrate(II) methanol tetrasolvate (ca 153 K) and bis[tris(1-methyl-1H-imidazol-2-yl)methanol-κ3N3]iron(III) bis[tetrachloroferrate(III)] chloride (redetermination, ca 153 K)",

abstract = "The first of the title compounds, [Fe(C12H15N6P)2][FeCl4]·4CH4O, is the first homoleptic bis(ligand)iron(II) species reported for this phosphorus bridgehead ligand; interestingly, the complex is isomorphous with its tris(1-methyl-1H-imidazol-2-yl)methanol counterpart, the second of the title compounds, [Fe(C13H16N6O)2][FeCl4]2Cl. In both compounds, the Fe atom of the cation lies on an inversion centre. The structure determinations presented here allow an interesting comparison of iron(II) and iron(III) species in similar coordination environments.",

author = "M.P. Batten and A.J. Canty and K.J. Cavell and T. Ruther and Brian Skelton and Allan White",

year = "2004",

doi = "10.1107/S0108270104010868",

language = "English",

volume = "C60",

pages = "m311--m313",

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publisher = "International Union of Crystallography",

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Batten, MP, Canty, AJ, Cavell, KJ, Ruther, T, Skelton, B & White, A 2004, 'Bis[tris(1-methyl-1H-imidazol-2-yl)-phosphine-κ3N3]iron(II) tetrachloroferrate(II) methanol tetrasolvate (ca 153 K) and bis[tris(1-methyl-1H-imidazol-2-yl)methanol-κ3N3]iron(III) bis[tetrachloroferrate(III)] chloride (redetermination, ca 153 K)', Acta Crystallographica Section C: Structural Chemistry, vol. C60, no. 7, pp. m311-m313. https://doi.org/10.1107/S0108270104010868

Bis[tris(1-methyl-1H-imidazol-2-yl)-phosphine-κ3N3]iron(II) tetrachloroferrate(II) methanol tetrasolvate (ca 153 K) and bis[tris(1-methyl-1H-imidazol-2-yl)methanol-κ3N3]iron(III) bis[tetrachloroferrate(III)] chloride (redetermination, ca 153 K). / Batten, M.P.; Canty, A.J.; Cavell, K.J.; Ruther, T.; Skelton, Brian; White, Allan.

In: Acta Crystallographica Section C: Structural Chemistry, Vol. C60, No. 7, 2004, p. m311-m313.

Research output: Contribution to journal › Article

TY - JOUR

T1 - Bis[tris(1-methyl-1H-imidazol-2-yl)-phosphine-κ3N3]iron(II) tetrachloroferrate(II) methanol tetrasolvate (ca 153 K) and bis[tris(1-methyl-1H-imidazol-2-yl)methanol-κ3N3]iron(III) bis[tetrachloroferrate(III)] chloride (redetermination, ca 153 K)

AU - Batten, M.P.

AU - Canty, A.J.

AU - Cavell, K.J.

AU - Ruther, T.

AU - Skelton, Brian

AU - White, Allan

PY - 2004

Y1 - 2004

N2 - The first of the title compounds, [Fe(C12H15N6P)2][FeCl4]·4CH4O, is the first homoleptic bis(ligand)iron(II) species reported for this phosphorus bridgehead ligand; interestingly, the complex is isomorphous with its tris(1-methyl-1H-imidazol-2-yl)methanol counterpart, the second of the title compounds, [Fe(C13H16N6O)2][FeCl4]2Cl. In both compounds, the Fe atom of the cation lies on an inversion centre. The structure determinations presented here allow an interesting comparison of iron(II) and iron(III) species in similar coordination environments.

AB - The first of the title compounds, [Fe(C12H15N6P)2][FeCl4]·4CH4O, is the first homoleptic bis(ligand)iron(II) species reported for this phosphorus bridgehead ligand; interestingly, the complex is isomorphous with its tris(1-methyl-1H-imidazol-2-yl)methanol counterpart, the second of the title compounds, [Fe(C13H16N6O)2][FeCl4]2Cl. In both compounds, the Fe atom of the cation lies on an inversion centre. The structure determinations presented here allow an interesting comparison of iron(II) and iron(III) species in similar coordination environments.

U2 - 10.1107/S0108270104010868

DO - 10.1107/S0108270104010868

M3 - Article

C2 - 15237144

VL - C60

SP - m311-m313

JO - Acta Crystallographica. Section C: Crystal Structure Communications

JF - Acta Crystallographica. Section C: Crystal Structure Communications

SN - 1600-5759

IS - 7

ER -

Batten MP, Canty AJ, Cavell KJ, Ruther T, Skelton B, White A. Bis[tris(1-methyl-1H-imidazol-2-yl)-phosphine-κ3N3]iron(II) tetrachloroferrate(II) methanol tetrasolvate (ca 153 K) and bis[tris(1-methyl-1H-imidazol-2-yl)methanol-κ3N3]iron(III) bis[tetrachloroferrate(III)] chloride (redetermination, ca 153 K). Acta Crystallographica Section C: Structural Chemistry. 2004;C60(7):m311-m313. https://doi.org/10.1107/S0108270104010868