TY - JOUR
T1 - Bis{2-[(pyridin-2-yl)methylideneamino]benzoato-κ3 N,N′,O}chromium(III) nitrate monohydrate
AU - Buvaylo, E.A.
AU - Kokozay, V.N.
AU - Vassilyeva, O.Y.
AU - Skelton, Brian
PY - 2014
Y1 - 2014
N2 - The title complex salt hydrate, [Cr(C13H9N 2O2)2]NO3·H2O, comprises discrete cations, nitrate anions and solvent water molecules. The Cr III atom is octahedrally coordinated by two anionic Schiff base ligands with the O atoms being cis. The two ligands differ significantly with dihedral angles between the pyridine and benzene rings of 4.8(2) and 24.9(2)°. The nitrate anion and solvent water molecule were modelled as being disordered, with the major components having site-occupancy values of 0.856(14) and 0.727(16), respectively. The crystal is built of alternating layers of cations and of anions plus water molecules, stacked along the c axis.
AB - The title complex salt hydrate, [Cr(C13H9N 2O2)2]NO3·H2O, comprises discrete cations, nitrate anions and solvent water molecules. The Cr III atom is octahedrally coordinated by two anionic Schiff base ligands with the O atoms being cis. The two ligands differ significantly with dihedral angles between the pyridine and benzene rings of 4.8(2) and 24.9(2)°. The nitrate anion and solvent water molecule were modelled as being disordered, with the major components having site-occupancy values of 0.856(14) and 0.727(16), respectively. The crystal is built of alternating layers of cations and of anions plus water molecules, stacked along the c axis.
U2 - 10.1107/S1600536814005649
DO - 10.1107/S1600536814005649
M3 - Article
VL - 70
SP - 1
EP - 9
JO - Acta Crystallographica. Section E: Structure Reports Online
JF - Acta Crystallographica. Section E: Structure Reports Online
SN - 1600-5368
IS - 4
ER -