Autocatalytic formation of fluorinated ferrocenophanes from 1,1′-bis(trifluorovinyl)ferrocene

Max Roemer; D. Lentz

doi:10.1039/c1cc11812a

Autocatalytic formation of fluorinated ferrocenophanes from 1,1′-bis(trifluorovinyl)ferrocene

Max Roemer
, D. Lentz

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

1,1′-Bis(trifluorovinyl)ferrocene is obtained in excellent yields from a Negishi type coupling reaction. Under certain redox conditions and in the presence of a suitable nucleophile, the highly reactive compound undergoes a transformation to fluorinated ferrocenophanes. Intra and intermolecular [2+2]-cycloaddition products are formed upon heating. © 2011 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	7239-7241
Journal	Chemical Communications
Volume	47
Issue number	25
DOIs	https://doi.org/10.1039/c1cc11812a
Publication status	Published - 2011

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title = "Autocatalytic formation of fluorinated ferrocenophanes from 1,1′-bis(trifluorovinyl)ferrocene",

abstract = "1,1′-Bis(trifluorovinyl)ferrocene is obtained in excellent yields from a Negishi type coupling reaction. Under certain redox conditions and in the presence of a suitable nucleophile, the highly reactive compound undergoes a transformation to fluorinated ferrocenophanes. Intra and intermolecular [2+2]-cycloaddition products are formed upon heating. {\textcopyright} 2011 The Royal Society of Chemistry.",

author = "Max Roemer and D. Lentz",

year = "2011",

doi = "10.1039/c1cc11812a",

language = "English",

volume = "47",

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journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

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T1 - Autocatalytic formation of fluorinated ferrocenophanes from 1,1′-bis(trifluorovinyl)ferrocene

AU - Roemer, Max

AU - Lentz, D.

PY - 2011

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N2 - 1,1′-Bis(trifluorovinyl)ferrocene is obtained in excellent yields from a Negishi type coupling reaction. Under certain redox conditions and in the presence of a suitable nucleophile, the highly reactive compound undergoes a transformation to fluorinated ferrocenophanes. Intra and intermolecular [2+2]-cycloaddition products are formed upon heating. © 2011 The Royal Society of Chemistry.

AB - 1,1′-Bis(trifluorovinyl)ferrocene is obtained in excellent yields from a Negishi type coupling reaction. Under certain redox conditions and in the presence of a suitable nucleophile, the highly reactive compound undergoes a transformation to fluorinated ferrocenophanes. Intra and intermolecular [2+2]-cycloaddition products are formed upon heating. © 2011 The Royal Society of Chemistry.

U2 - 10.1039/c1cc11812a

DO - 10.1039/c1cc11812a

M3 - Article

SN - 1359-7345

VL - 47

SP - 7239

EP - 7241

JO - Chemical Communications

JF - Chemical Communications

IS - 25

ER -

Autocatalytic formation of fluorinated ferrocenophanes from 1,1′-bis(trifluorovinyl)ferrocene

Abstract

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