Asymmetric Synthesis and Stereochemical Assignment of 12C/13C Isotopomers

Tomoya Miura, Takayuki Nakamuro, Yuuya Nagata, Daisuke Moriyama, Scott G. Stewart, Masahiro Murakami

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A synthesis of chiral hydrocarbons having C1 axis and C3 symmetry, which owe their chirality due to asymmetrical distribution of 12C/13C isotopes, is reported. Their absolute configurations assigned using the vibrational circular dichroism technique conform with those deduced from the absolute configurations of the parent α-formyl cyclopropanes.

Original languageEnglish
Pages (from-to)13341-13345
Number of pages5
JournalJournal of the American Chemical Society
Volume141
Issue number34
DOIs
Publication statusPublished - 28 Aug 2019

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