Asymmetric Synthesis and Stereochemical Assignment of 12C/13C Isotopomers

Tomoya Miura; Takayuki Nakamuro; Yuuya Nagata; Daisuke Moriyama; Scott G. Stewart; Masahiro Murakami

doi:10.1021/jacs.9b07181

Asymmetric Synthesis and Stereochemical Assignment of ¹²C/¹³C Isotopomers

Tomoya Miura, Takayuki Nakamuro, Yuuya Nagata, Daisuke Moriyama, Scott G. Stewart, Masahiro Murakami

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

A synthesis of chiral hydrocarbons having C₁ axis and C₃ symmetry, which owe their chirality due to asymmetrical distribution of ¹²C/¹³C isotopes, is reported. Their absolute configurations assigned using the vibrational circular dichroism technique conform with those deduced from the absolute configurations of the parent α-formyl cyclopropanes.

Original language	English
Pages (from-to)	13341-13345
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	141
Issue number	34
DOIs	https://doi.org/10.1021/jacs.9b07181
Publication status	Published - 28 Aug 2019

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title = "Asymmetric Synthesis and Stereochemical Assignment of 12C/13C Isotopomers",

abstract = "A synthesis of chiral hydrocarbons having C1 axis and C3 symmetry, which owe their chirality due to asymmetrical distribution of 12C/13C isotopes, is reported. Their absolute configurations assigned using the vibrational circular dichroism technique conform with those deduced from the absolute configurations of the parent α-formyl cyclopropanes.",

author = "Tomoya Miura and Takayuki Nakamuro and Yuuya Nagata and Daisuke Moriyama and Stewart, {Scott G.} and Masahiro Murakami",

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AU - Miura, Tomoya

AU - Nakamuro, Takayuki

AU - Nagata, Yuuya

AU - Moriyama, Daisuke

AU - Stewart, Scott G.

AU - Murakami, Masahiro

PY - 2019/8/28

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N2 - A synthesis of chiral hydrocarbons having C1 axis and C3 symmetry, which owe their chirality due to asymmetrical distribution of 12C/13C isotopes, is reported. Their absolute configurations assigned using the vibrational circular dichroism technique conform with those deduced from the absolute configurations of the parent α-formyl cyclopropanes.

AB - A synthesis of chiral hydrocarbons having C1 axis and C3 symmetry, which owe their chirality due to asymmetrical distribution of 12C/13C isotopes, is reported. Their absolute configurations assigned using the vibrational circular dichroism technique conform with those deduced from the absolute configurations of the parent α-formyl cyclopropanes.

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DO - 10.1021/jacs.9b07181

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EP - 13345

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 34

ER -

Asymmetric Synthesis and Stereochemical Assignment of ¹²C/¹³C Isotopomers

Abstract

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