Alkynyl-functionalised phosporous compounds and their reaction with metals and metal complexes of 6-amino-6-methyl-1,4-diazacycloheptane derivatives

Alison Barnes

Research output: ThesisDoctoral Thesis

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Abstract

[Truncated abstract] This thesis is presented in two parts. The first part describes the synthesis of tertiary phosphine compounds with alkyne functionalised pendant arms (for example, I). The reactions of these mixed phosphine/alkyne donor ligands with various tungsten, rhodium and nickel sources, were investigated, in an attempt to synthesize new organometallic cages such as II.
Original languageEnglish
QualificationDoctor of Philosophy
Publication statusUnpublished - 2011

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