TY - JOUR
T1 - A route to new methylpalladium(II) carbene complexes
AU - Green, M.J.
AU - Cavell, K.J.
AU - Skelton, Brian
AU - White, Allan
PY - 1998
Y1 - 1998
N2 - The nucleophilic carbene, 1,3-dimethylimidazolin-2-ylidene, reacts with PdClMe(cod) to produce the first methylpalladium(II) carbene complex, [PdMe(1,3-dimethylimidazolin-2-ylidene)(mu-Cl)](2) 1, from which the preparation of other methylpalladium carbene complexes may proceed, and the crystal structure of one such complex, [PdMe(1,3-dimethylimidazolin-2-ylidene)(NC5H4CO2-2)], is reported. (C) 1998 Elsevier Science S.A. All rights reserved.
AB - The nucleophilic carbene, 1,3-dimethylimidazolin-2-ylidene, reacts with PdClMe(cod) to produce the first methylpalladium(II) carbene complex, [PdMe(1,3-dimethylimidazolin-2-ylidene)(mu-Cl)](2) 1, from which the preparation of other methylpalladium carbene complexes may proceed, and the crystal structure of one such complex, [PdMe(1,3-dimethylimidazolin-2-ylidene)(NC5H4CO2-2)], is reported. (C) 1998 Elsevier Science S.A. All rights reserved.
U2 - 10.1016/S0022-328X(97)00671-2
DO - 10.1016/S0022-328X(97)00671-2
M3 - Article
VL - 554
SP - 175
EP - 179
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - N/A
ER -