A route to new methylpalladium(II) carbene complexes

M.J. Green, K.J. Cavell, Brian Skelton, Allan White

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Abstract

The nucleophilic carbene, 1,3-dimethylimidazolin-2-ylidene, reacts with PdClMe(cod) to produce the first methylpalladium(II) carbene complex, [PdMe(1,3-dimethylimidazolin-2-ylidene)(mu-Cl)](2) 1, from which the preparation of other methylpalladium carbene complexes may proceed, and the crystal structure of one such complex, [PdMe(1,3-dimethylimidazolin-2-ylidene)(NC5H4CO2-2)], is reported. (C) 1998 Elsevier Science S.A. All rights reserved.
Original languageEnglish
Pages (from-to)175-179
JournalJournal of Organometallic Chemistry
Volume554
Issue numberN/A
DOIs
Publication statusPublished - 1998

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