A Percyanovinylidene-Ruthenium Complex, Ru{=C=C-5(CN)(3)[=C(CN)(2)](2)}(dppe)Cp

M.I. Bruce; J.C. Morris; B.K. Nicholson; Brian Skelton; Allan White; N.N. Zaitseva

doi:10.1021/om1010885

A Percyanovinylidene-Ruthenium Complex, Ru{=C=C-5(CN)(3)[=C(CN)(2)](2)}(dppe)Cp

M.I. Bruce
, J.C. Morris
, B.K. Nicholson
, Brian Skelton
, Allan White
, N.N. Zaitseva

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The reaction between Ru(C CC CAg)(dppe)Cp* and tene affords a novel percyanovinylidene complex by an unusual decyano-dimerization reaction of the cyanocarbon with the diynyl fragment. This complex is also obtained from tene and Ru{C CC C[Au(PPh3)]}(dppe)Cp*, together with Ru{C CC[ C(CN)(2)]C[Au(PPh3)]=C(CN)(2)}(dppe)Cp*, formed by the anticipated [2 + 2] cycloaddition and subsequent ring-opening reactions.

Original language	English
Pages (from-to)	653-656
Journal	Organometallics
Volume	30
DOIs	https://doi.org/10.1021/om1010885
Publication status	Published - 2011

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@article{946e3263c0d043dfb0eaebb9291196ea,

title = "A Percyanovinylidene-Ruthenium Complex, Ru\{=C=C-5(CN)(3)[=C(CN)(2)](2)\}(dppe)Cp",

abstract = "The reaction between Ru(C CC CAg)(dppe)Cp* and tene affords a novel percyanovinylidene complex by an unusual decyano-dimerization reaction of the cyanocarbon with the diynyl fragment. This complex is also obtained from tene and Ru\{C CC C[Au(PPh3)]\}(dppe)Cp*, together with Ru\{C CC[ C(CN)(2)]C[Au(PPh3)]=C(CN)(2)\}(dppe)Cp*, formed by the anticipated [2 + 2] cycloaddition and subsequent ring-opening reactions.",

author = "M.I. Bruce and J.C. Morris and B.K. Nicholson and Brian Skelton and Allan White and N.N. Zaitseva",

year = "2011",

doi = "10.1021/om1010885",

language = "English",

volume = "30",

pages = "653--656",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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TY - JOUR

T1 - A Percyanovinylidene-Ruthenium Complex, Ru{=C=C-5(CN)(3)[=C(CN)(2)](2)}(dppe)Cp

AU - Bruce, M.I.

AU - Morris, J.C.

AU - Nicholson, B.K.

AU - Skelton, Brian

AU - White, Allan

AU - Zaitseva, N.N.

PY - 2011

Y1 - 2011

N2 - The reaction between Ru(C CC CAg)(dppe)Cp* and tene affords a novel percyanovinylidene complex by an unusual decyano-dimerization reaction of the cyanocarbon with the diynyl fragment. This complex is also obtained from tene and Ru{C CC C[Au(PPh3)]}(dppe)Cp*, together with Ru{C CC[ C(CN)(2)]C[Au(PPh3)]=C(CN)(2)}(dppe)Cp*, formed by the anticipated [2 + 2] cycloaddition and subsequent ring-opening reactions.

AB - The reaction between Ru(C CC CAg)(dppe)Cp* and tene affords a novel percyanovinylidene complex by an unusual decyano-dimerization reaction of the cyanocarbon with the diynyl fragment. This complex is also obtained from tene and Ru{C CC C[Au(PPh3)]}(dppe)Cp*, together with Ru{C CC[ C(CN)(2)]C[Au(PPh3)]=C(CN)(2)}(dppe)Cp*, formed by the anticipated [2 + 2] cycloaddition and subsequent ring-opening reactions.

U2 - 10.1021/om1010885

DO - 10.1021/om1010885

M3 - Article

SN - 0276-7333

VL - 30

SP - 653

EP - 656

JO - Organometallics

JF - Organometallics

ER -

A Percyanovinylidene-Ruthenium Complex, Ru{=C=C-5(CN)(3)[=C(CN)(2)](2)}(dppe)Cp

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