A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres : molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16)

  • A.B. Antonova
  • , M.I. Bruce
  • , B.G. Ellis
  • , M. Gaudio
  • , P.A. Humphrey
  • , M. Jevric
  • , G. Melino
  • , B.K. Nicholson
  • , G.J. Perkins
  • , Brian Skelton
  • , B. Stapleton
  • , Allan White
  • , N.N. Zaitseva

Research output: Contribution to journalArticlepeer-review

Abstract

Elimination of AuX(PR3) (X = halogen, R = Ph, tol) occurs readily in reactions between compounds containing C(sp)– or C(sp2)–X bonds and alkynyl or polyynyl gold(I) complexes; this reaction has been applied to the syntheses of complexes containing a variety of metal centres linked by Cn chains (n up to 16).
Original languageEnglish
Pages (from-to)960-961
JournalChemical Communications
Volume8
Issue number8
Publication statusPublished - 2004

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