A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres : molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16)

A.B. Antonova; M.I. Bruce; B.G. Ellis; M. Gaudio; P.A. Humphrey; M. Jevric; G. Melino; B.K. Nicholson; G.J. Perkins; Brian Skelton; B. Stapleton; Allan White; N.N. Zaitseva

A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres : molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16)

A.B. Antonova, M.I. Bruce, B.G. Ellis, M. Gaudio, P.A. Humphrey, M. Jevric, G. Melino, B.K. Nicholson, G.J. Perkins, Brian Skelton, B. Stapleton, Allan White, N.N. Zaitseva

Research output: Contribution to journal › Article › peer-review

110 Citations (Scopus)

Abstract

Elimination of AuX(PR3) (X = halogen, R = Ph, tol) occurs readily in reactions between compounds containing C(sp)– or C(sp2)–X bonds and alkynyl or polyynyl gold(I) complexes; this reaction has been applied to the syntheses of complexes containing a variety of metal centres linked by Cn chains (n up to 16).

Original language	English
Pages (from-to)	960-961
Journal	Chemical Communications
Volume	8
Issue number	8
Publication status	Published - 2004

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Antonova, A. B., Bruce, M. I., Ellis, B. G., Gaudio, M., Humphrey, P. A., Jevric, M., Melino, G., Nicholson, B. K., Perkins, G. J., Skelton, B., Stapleton, B., White, A., & Zaitseva, N. N. (2004). A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres : molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16). Chemical Communications, 8(8), 960-961.

@article{388cd689a26d4b859cfeedb13157a75c,

title = "A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres : molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16)",

abstract = "Elimination of AuX(PR3) (X = halogen, R = Ph, tol) occurs readily in reactions between compounds containing C(sp)– or C(sp2)–X bonds and alkynyl or polyynyl gold(I) complexes; this reaction has been applied to the syntheses of complexes containing a variety of metal centres linked by Cn chains (n up to 16).",

author = "A.B. Antonova and M.I. Bruce and B.G. Ellis and M. Gaudio and P.A. Humphrey and M. Jevric and G. Melino and B.K. Nicholson and G.J. Perkins and Brian Skelton and B. Stapleton and Allan White and N.N. Zaitseva",

year = "2004",

language = "English",

volume = "8",

pages = "960--961",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "ROYAL SOC CHEMISTRY",

number = "8",

}

Antonova, AB, Bruce, MI, Ellis, BG, Gaudio, M, Humphrey, PA, Jevric, M, Melino, G, Nicholson, BK, Perkins, GJ, Skelton, B, Stapleton, B, White, A & Zaitseva, NN 2004, 'A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres : molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16)', Chemical Communications, vol. 8, no. 8, pp. 960-961.

A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres : molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16). / Antonova, A.B.; Bruce, M.I.; Ellis, B.G. et al.
In: Chemical Communications, Vol. 8, No. 8, 2004, p. 960-961.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres : molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16)

AU - Antonova, A.B.

AU - Bruce, M.I.

AU - Ellis, B.G.

AU - Gaudio, M.

AU - Humphrey, P.A.

AU - Jevric, M.

AU - Melino, G.

AU - Nicholson, B.K.

AU - Perkins, G.J.

AU - Skelton, Brian

AU - Stapleton, B.

AU - White, Allan

AU - Zaitseva, N.N.

PY - 2004

Y1 - 2004

N2 - Elimination of AuX(PR3) (X = halogen, R = Ph, tol) occurs readily in reactions between compounds containing C(sp)– or C(sp2)–X bonds and alkynyl or polyynyl gold(I) complexes; this reaction has been applied to the syntheses of complexes containing a variety of metal centres linked by Cn chains (n up to 16).

AB - Elimination of AuX(PR3) (X = halogen, R = Ph, tol) occurs readily in reactions between compounds containing C(sp)– or C(sp2)–X bonds and alkynyl or polyynyl gold(I) complexes; this reaction has been applied to the syntheses of complexes containing a variety of metal centres linked by Cn chains (n up to 16).

M3 - Article

SN - 1359-7345

VL - 8

SP - 960

EP - 961

JO - Chemical Communications

JF - Chemical Communications

IS - 8

ER -

A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres : molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16)

Abstract

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