A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres : molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16)

A.B. Antonova, M.I. Bruce, B.G. Ellis, M. Gaudio, P.A. Humphrey, M. Jevric, G. Melino, B.K. Nicholson, G.J. Perkins, Brian Skelton, B. Stapleton, Allan White, N.N. Zaitseva

Research output: Contribution to journalArticlepeer-review

111 Citations (Scopus)

Abstract

Elimination of AuX(PR3) (X = halogen, R = Ph, tol) occurs readily in reactions between compounds containing C(sp)– or C(sp2)–X bonds and alkynyl or polyynyl gold(I) complexes; this reaction has been applied to the syntheses of complexes containing a variety of metal centres linked by Cn chains (n up to 16).
Original languageEnglish
Pages (from-to)960-961
JournalChemical Communications
Volume8
Issue number8
Publication statusPublished - 2004

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