A novel heterometallic μ4-oxo-bridged complex based on an octahedral Cd2Cu4 skeleton via the reaction of elemental copper, cadmium acetate and amino alcohol

E.A. Vinogradova; V.N. Kokozay; O.Y. Vassilyeva; Brian Skelton

doi:10.1016/S1387-7003(02)00688-3

A novel heterometallic μ4-oxo-bridged complex based on an octahedral Cd2Cu4 skeleton via the reaction of elemental copper, cadmium acetate and amino alcohol

E.A. Vinogradova
, V.N. Kokozay
, O.Y. Vassilyeva
, Brian Skelton

Centre for Microscopy, Characterisation & Analysis

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The reaction of copper powder in dmso with cadmium acetate hydrate and 2-dimethylaminoethanol (HL), in open air, afforded [Cd2Cu4(μ4-O)(O2CMe)6L4]·2H2O with a metal skeleton that approximates an octahedron. The copper atoms are tetrahedrally arranged about the oxygen atom in a considerably distorted fashion. The amino alkoxo and acetate ligands display a variety of bonding modes in the complex.

Original language	English
Pages (from-to)	82-85
Journal	Inorganic Chemistry Communications
Volume	6
Issue number	1
DOIs	https://doi.org/10.1016/S1387-7003(02)00688-3
Publication status	Published - 2003

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title = "A novel heterometallic μ4-oxo-bridged complex based on an octahedral Cd2Cu4 skeleton via the reaction of elemental copper, cadmium acetate and amino alcohol",

abstract = "The reaction of copper powder in dmso with cadmium acetate hydrate and 2-dimethylaminoethanol (HL), in open air, afforded [Cd2Cu4(μ4-O)(O2CMe)6L4]·2H2O with a metal skeleton that approximates an octahedron. The copper atoms are tetrahedrally arranged about the oxygen atom in a considerably distorted fashion. The amino alkoxo and acetate ligands display a variety of bonding modes in the complex.",

author = "E.A. Vinogradova and V.N. Kokozay and O.Y. Vassilyeva and Brian Skelton",

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T1 - A novel heterometallic μ4-oxo-bridged complex based on an octahedral Cd2Cu4 skeleton via the reaction of elemental copper, cadmium acetate and amino alcohol

AU - Vinogradova, E.A.

AU - Kokozay, V.N.

AU - Vassilyeva, O.Y.

AU - Skelton, Brian

PY - 2003

Y1 - 2003

N2 - The reaction of copper powder in dmso with cadmium acetate hydrate and 2-dimethylaminoethanol (HL), in open air, afforded [Cd2Cu4(μ4-O)(O2CMe)6L4]·2H2O with a metal skeleton that approximates an octahedron. The copper atoms are tetrahedrally arranged about the oxygen atom in a considerably distorted fashion. The amino alkoxo and acetate ligands display a variety of bonding modes in the complex.

AB - The reaction of copper powder in dmso with cadmium acetate hydrate and 2-dimethylaminoethanol (HL), in open air, afforded [Cd2Cu4(μ4-O)(O2CMe)6L4]·2H2O with a metal skeleton that approximates an octahedron. The copper atoms are tetrahedrally arranged about the oxygen atom in a considerably distorted fashion. The amino alkoxo and acetate ligands display a variety of bonding modes in the complex.

U2 - 10.1016/S1387-7003(02)00688-3

DO - 10.1016/S1387-7003(02)00688-3

M3 - Article

SN - 1387-7003

VL - 6

SP - 82

EP - 85

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 1

ER -

A novel heterometallic μ4-oxo-bridged complex based on an octahedral Cd2Cu4 skeleton via the reaction of elemental copper, cadmium acetate and amino alcohol

Abstract

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