TY - JOUR
T1 - A novel heterometallic μ4-oxo-bridged complex based on an octahedral Cd2Cu4 skeleton via the reaction of elemental copper, cadmium acetate and amino alcohol
AU - Vinogradova, E.A.
AU - Kokozay, V.N.
AU - Vassilyeva, O.Y.
AU - Skelton, Brian
PY - 2003
Y1 - 2003
N2 - The reaction of copper powder in dmso with cadmium acetate hydrate and 2-dimethylaminoethanol (HL), in open air, afforded [Cd2Cu4(μ4-O)(O2CMe)6L4]·2H2O with a metal skeleton that approximates an octahedron. The copper atoms are tetrahedrally arranged about the oxygen atom in a considerably distorted fashion. The amino alkoxo and acetate ligands display a variety of bonding modes in the complex.
AB - The reaction of copper powder in dmso with cadmium acetate hydrate and 2-dimethylaminoethanol (HL), in open air, afforded [Cd2Cu4(μ4-O)(O2CMe)6L4]·2H2O with a metal skeleton that approximates an octahedron. The copper atoms are tetrahedrally arranged about the oxygen atom in a considerably distorted fashion. The amino alkoxo and acetate ligands display a variety of bonding modes in the complex.
U2 - 10.1016/S1387-7003(02)00688-3
DO - 10.1016/S1387-7003(02)00688-3
M3 - Article
SN - 1387-7003
VL - 6
SP - 82
EP - 85
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 1
ER -