TY - JOUR
T1 - A new ester substituted heteroscorpionate ligand
AU - Alidori, S.
AU - Pellei, M.
AU - Pettinari, C.
AU - Santini, C.
AU - Skelton, Brian
AU - White, Allan
PY - 2004
Y1 - 2004
N2 - The new dihydrobis(3 -carboxyethyl-5-methylpyrazolyl)borate ligand Bp(COOET,Me) is prepared as its potassium salt in kerosene solution, using ethyl 3-methylpyrazole-5-carboxylate and KBH4, through careful temperature control. Bp(COOET,Me) reacts with CuCl and PPh3 to yield the {Cu(Bp(COOET,Me))PPh3} complex. BPCOOET,Me and {Cu(BPCOOET, me)PPh3) have been fully characterized by elemental analyses and FT-IR in the solid state and by NMR (H-1, C-13 and (31)p) spectroscopy and electrospray ionization mass spectrometry in solution. A single crystal structural characterization is reported for {Cu(Bp(COOET,Me))PPh3]. (C) 2004 Elsevier B.V. All rights reserved.
AB - The new dihydrobis(3 -carboxyethyl-5-methylpyrazolyl)borate ligand Bp(COOET,Me) is prepared as its potassium salt in kerosene solution, using ethyl 3-methylpyrazole-5-carboxylate and KBH4, through careful temperature control. Bp(COOET,Me) reacts with CuCl and PPh3 to yield the {Cu(Bp(COOET,Me))PPh3} complex. BPCOOET,Me and {Cu(BPCOOET, me)PPh3) have been fully characterized by elemental analyses and FT-IR in the solid state and by NMR (H-1, C-13 and (31)p) spectroscopy and electrospray ionization mass spectrometry in solution. A single crystal structural characterization is reported for {Cu(Bp(COOET,Me))PPh3]. (C) 2004 Elsevier B.V. All rights reserved.
U2 - 10.1016/j.inoche.2004.07.017
DO - 10.1016/j.inoche.2004.07.017
M3 - Article
SN - 1387-7003
VL - 7
SP - 1075
EP - 1077
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 9
ER -