TY - JOUR
T1 - A new 2D heterometallic Cu/Cd mixed-anion polymer with dicyanamide and thiocyanate bridges formed via the reaction of elemental copper, cadmium dicyanamide and ethylenediamine
AU - Nesterova (pryma), O.V.
AU - Petrusenko, S.R.
AU - Kokozay, V.N.
AU - Skelton, Brian
AU - Linert, W.
PY - 2004
Y1 - 2004
N2 - The new heterometallic 2D polymer [Cu(en)(2)Cd(dca)(2)(SCN)(2)]n (en = ethylenediamine; dca = dicyanamide, N(CN)(2)(-)), the first example of a compound containing the unique mixed-anion Cd(dca)2(SCN, fragment, has been prepared from copper powder, cadmium dicyanamide, ammonium thiocyanate and ethylenediamine in methanol solution in air. The polymeric sheets of the compound comprise two different rings - 28-membered [CU2Cd4( mu(1,5)-dca)(2)( mu(1,3)-NCS)(4)] macrocycles in which two 12-membered [Cd-2(mu(1.5)-dca)(2)] rings form sections. (C) 2004 Elsevier B.V. All rights reserved.
AB - The new heterometallic 2D polymer [Cu(en)(2)Cd(dca)(2)(SCN)(2)]n (en = ethylenediamine; dca = dicyanamide, N(CN)(2)(-)), the first example of a compound containing the unique mixed-anion Cd(dca)2(SCN, fragment, has been prepared from copper powder, cadmium dicyanamide, ammonium thiocyanate and ethylenediamine in methanol solution in air. The polymeric sheets of the compound comprise two different rings - 28-membered [CU2Cd4( mu(1,5)-dca)(2)( mu(1,3)-NCS)(4)] macrocycles in which two 12-membered [Cd-2(mu(1.5)-dca)(2)] rings form sections. (C) 2004 Elsevier B.V. All rights reserved.
U2 - 10.1016/j.inoche.2004.01.004
DO - 10.1016/j.inoche.2004.01.004
M3 - Article
SN - 1387-7003
VL - 7
SP - 450
EP - 454
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 3
ER -