Abstract
The crystal structure and magnetic properties of the compound Na-5[Mn(L-tart)2]center dot 12H(2)O ( 1, L-tart = L-tartrate) have been investigated over the pressure range 0.34-3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.
Original language | English |
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Pages (from-to) | 18324-18328 |
Number of pages | 5 |
Journal | Dalton Transactions |
Volume | 44 |
Issue number | 42 |
DOIs | |
Publication status | Published - 2015 |
Externally published | Yes |