A high-pressure crystallographic and magnetic study of Na-5[Mn(L-tart)2]center dot 12H(2)O (L-tart = L-tartrate)

Gavin A. Craig; Christopher H. Woodall; Scott C. McKellar; Michael R. Probert; Konstantin V. Kamenev; Stephen A. Moggach; Euan K. Brechin; Simon Parsons; Mark Murrie

doi:10.1039/c5dt03320a

A high-pressure crystallographic and magnetic study of Na-5[Mn(L-tart)2]center dot 12H(2)O (L-tart = L-tartrate)

Gavin A. Craig, Christopher H. Woodall, Scott C. McKellar, Michael R. Probert, Konstantin V. Kamenev, Stephen A. Moggach, Euan K. Brechin, Simon Parsons, Mark Murrie

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The crystal structure and magnetic properties of the compound Na-5[Mn(L-tart)2]center dot 12H(2)O ( 1, L-tart = L-tartrate) have been investigated over the pressure range 0.34-3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.

Original language	English
Pages (from-to)	18324-18328
Number of pages	5
Journal	Dalton Transactions
Volume	44
Issue number	42
DOIs	https://doi.org/10.1039/c5dt03320a
Publication status	Published - 2015
Externally published	Yes

Access to Document

10.1039/c5dt03320a

Cite this

@article{2fb4f64a8952404891562f3c0abd1c02,

title = "A high-pressure crystallographic and magnetic study of Na-5[Mn(L-tart)2]center dot 12H(2)O (L-tart = L-tartrate)",

abstract = "The crystal structure and magnetic properties of the compound Na-5[Mn(L-tart)2]center dot 12H(2)O ( 1, L-tart = L-tartrate) have been investigated over the pressure range 0.34-3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.",

keywords = "X-RAY-DIFFRACTION, COORDINATION CHEMISTRY, COMPLEX, PIEZOCHROMISM, TEMPERATURE, ANVIL, CELL",

author = "Craig, {Gavin A.} and Woodall, {Christopher H.} and McKellar, {Scott C.} and Probert, {Michael R.} and Kamenev, {Konstantin V.} and Moggach, {Stephen A.} and Brechin, {Euan K.} and Simon Parsons and Mark Murrie",

year = "2015",

doi = "10.1039/c5dt03320a",

language = "English",

volume = "44",

pages = "18324--18328",

journal = "Dalton Transactions: the international journal for inorganic, organometallic and bioinorganic chemistry",

issn = "1477-9226",

publisher = "ROYAL SOC CHEMISTRY",

number = "42",

}

TY - JOUR

T1 - A high-pressure crystallographic and magnetic study of Na-5[Mn(L-tart)2]center dot 12H(2)O (L-tart = L-tartrate)

AU - Craig, Gavin A.

AU - Woodall, Christopher H.

AU - McKellar, Scott C.

AU - Probert, Michael R.

AU - Kamenev, Konstantin V.

AU - Moggach, Stephen A.

AU - Brechin, Euan K.

AU - Parsons, Simon

AU - Murrie, Mark

PY - 2015

Y1 - 2015

N2 - The crystal structure and magnetic properties of the compound Na-5[Mn(L-tart)2]center dot 12H(2)O ( 1, L-tart = L-tartrate) have been investigated over the pressure range 0.34-3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.

AB - The crystal structure and magnetic properties of the compound Na-5[Mn(L-tart)2]center dot 12H(2)O ( 1, L-tart = L-tartrate) have been investigated over the pressure range 0.34-3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.

KW - X-RAY-DIFFRACTION

KW - COORDINATION CHEMISTRY

KW - COMPLEX

KW - PIEZOCHROMISM

KW - TEMPERATURE

KW - ANVIL

KW - CELL

U2 - 10.1039/c5dt03320a

DO - 10.1039/c5dt03320a

M3 - Article

VL - 44

SP - 18324

EP - 18328

JO - Dalton Transactions: the international journal for inorganic, organometallic and bioinorganic chemistry

JF - Dalton Transactions: the international journal for inorganic, organometallic and bioinorganic chemistry

SN - 1477-9226

IS - 42

ER -

A high-pressure crystallographic and magnetic study of Na-5[Mn(L-tart)2]center dot 12H(2)O (L-tart = L-tartrate)

Abstract

Access to Document

Fingerprint

Cite this