Abstract
| Original language | English |
|---|---|
| Pages (from-to) | m246-m248 |
| Journal | Acta Crystallographica. Section C: Crystal Structure Communications |
| Volume | 62 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - 2006 |
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A heterotrimetallic Cu-Co-Zn complex with the 2,2'-iminodiethanol ligand. / Nesterov, D.S.; Kokozay, V.N.; Skelton, Brian.
In: Acta Crystallographica. Section C: Crystal Structure Communications, Vol. 62, No. 6, 2006, p. m246-m248.Research output: Contribution to journal › Article
TY - JOUR
T1 - A heterotrimetallic Cu-Co-Zn complex with the 2,2'-iminodiethanol ligand
AU - Nesterov, D.S.
AU - Kokozay, V.N.
AU - Skelton, Brian
PY - 2006
Y1 - 2006
N2 - The crystal structure of the title compound, triacetato-1 kappa O;3 kappa O-4,O'-(2,2'-iminodiethanol)-1 kappa O-3,N,O'bis(mu-2,2'-iminodiethanolato)1 kappa O-2: 2 kappa O-6,N,O':3 kappa O-2'-cobalt(III)copper(II)-zinc(II), [CoCuZn(C4H9NO2)(2)(C2H3O2)(3)(C4H11NO2)], shows a molecule with a triangular three-metal core. The metal sites were refined with full occupancies, but the possibility that the Zn and Cu positions are actually mixed Cu/Zn sites cannot be excluded. The intermetallic Cu center dot center dot center dot Co and Co center dot center dot center dot Zn distances are 2.924 (3) and 2.906 (3) angstrom, respectively. The neutral molecules are held together by N-H center dot center dot center dot O hydrogen bonds involving amine groups from the 2,2'-iminodiethanol ligands and acetate groups to build two-dimensional layers.
AB - The crystal structure of the title compound, triacetato-1 kappa O;3 kappa O-4,O'-(2,2'-iminodiethanol)-1 kappa O-3,N,O'bis(mu-2,2'-iminodiethanolato)1 kappa O-2: 2 kappa O-6,N,O':3 kappa O-2'-cobalt(III)copper(II)-zinc(II), [CoCuZn(C4H9NO2)(2)(C2H3O2)(3)(C4H11NO2)], shows a molecule with a triangular three-metal core. The metal sites were refined with full occupancies, but the possibility that the Zn and Cu positions are actually mixed Cu/Zn sites cannot be excluded. The intermetallic Cu center dot center dot center dot Co and Co center dot center dot center dot Zn distances are 2.924 (3) and 2.906 (3) angstrom, respectively. The neutral molecules are held together by N-H center dot center dot center dot O hydrogen bonds involving amine groups from the 2,2'-iminodiethanol ligands and acetate groups to build two-dimensional layers.
U2 - 10.1107/S010827010601523X
DO - 10.1107/S010827010601523X
M3 - Article
VL - 62
SP - m246-m248
JO - Acta Crystallographica Section C: Structural Chemistry
JF - Acta Crystallographica Section C: Structural Chemistry
SN - 1600-5759
IS - 6
ER -