A heterotrimetallic Cu-Co-Zn complex with the 2,2'-iminodiethanol ligand

D.S. Nesterov, V.N. Kokozay, Brian Skelton

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The crystal structure of the title compound, triacetato-1 kappa O;3 kappa O-4,O'-(2,2'-iminodiethanol)-1 kappa O-3,N,O'bis(mu-2,2'-iminodiethanolato)1 kappa O-2: 2 kappa O-6,N,O':3 kappa O-2'-cobalt(III)copper(II)-zinc(II), [CoCuZn(C4H9NO2)(2)(C2H3O2)(3)(C4H11NO2)], shows a molecule with a triangular three-metal core. The metal sites were refined with full occupancies, but the possibility that the Zn and Cu positions are actually mixed Cu/Zn sites cannot be excluded. The intermetallic Cu center dot center dot center dot Co and Co center dot center dot center dot Zn distances are 2.924 (3) and 2.906 (3) angstrom, respectively. The neutral molecules are held together by N-H center dot center dot center dot O hydrogen bonds involving amine groups from the 2,2'-iminodiethanol ligands and acetate groups to build two-dimensional layers.
Original languageEnglish
Pages (from-to)m246-m248
JournalActa Crystallographica. Section C: Crystal Structure Communications
Volume62
Issue number6
DOIs
Publication statusPublished - 2006

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Metals
Ligands
ligands
Molecules
Cobalt
Intermetallics
Amines
Zinc
Copper
Hydrogen bonds
Acetates
Crystal structure
2,2'-iminodiethanol
metals
intermetallics
molecules
acetates
amines
cobalt
zinc

Cite this

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title = "A heterotrimetallic Cu-Co-Zn complex with the 2,2'-iminodiethanol ligand",
abstract = "The crystal structure of the title compound, triacetato-1 kappa O;3 kappa O-4,O'-(2,2'-iminodiethanol)-1 kappa O-3,N,O'bis(mu-2,2'-iminodiethanolato)1 kappa O-2: 2 kappa O-6,N,O':3 kappa O-2'-cobalt(III)copper(II)-zinc(II), [CoCuZn(C4H9NO2)(2)(C2H3O2)(3)(C4H11NO2)], shows a molecule with a triangular three-metal core. The metal sites were refined with full occupancies, but the possibility that the Zn and Cu positions are actually mixed Cu/Zn sites cannot be excluded. The intermetallic Cu center dot center dot center dot Co and Co center dot center dot center dot Zn distances are 2.924 (3) and 2.906 (3) angstrom, respectively. The neutral molecules are held together by N-H center dot center dot center dot O hydrogen bonds involving amine groups from the 2,2'-iminodiethanol ligands and acetate groups to build two-dimensional layers.",
author = "D.S. Nesterov and V.N. Kokozay and Brian Skelton",
year = "2006",
doi = "10.1107/S010827010601523X",
language = "English",
volume = "62",
pages = "m246--m248",
journal = "Acta Crystallographica Section C: Structural Chemistry",
issn = "1600-5759",
publisher = "International Union of Crystallography",
number = "6",

}

A heterotrimetallic Cu-Co-Zn complex with the 2,2'-iminodiethanol ligand. / Nesterov, D.S.; Kokozay, V.N.; Skelton, Brian.

In: Acta Crystallographica. Section C: Crystal Structure Communications, Vol. 62, No. 6, 2006, p. m246-m248.

Research output: Contribution to journalArticle

TY - JOUR

T1 - A heterotrimetallic Cu-Co-Zn complex with the 2,2'-iminodiethanol ligand

AU - Nesterov, D.S.

AU - Kokozay, V.N.

AU - Skelton, Brian

PY - 2006

Y1 - 2006

N2 - The crystal structure of the title compound, triacetato-1 kappa O;3 kappa O-4,O'-(2,2'-iminodiethanol)-1 kappa O-3,N,O'bis(mu-2,2'-iminodiethanolato)1 kappa O-2: 2 kappa O-6,N,O':3 kappa O-2'-cobalt(III)copper(II)-zinc(II), [CoCuZn(C4H9NO2)(2)(C2H3O2)(3)(C4H11NO2)], shows a molecule with a triangular three-metal core. The metal sites were refined with full occupancies, but the possibility that the Zn and Cu positions are actually mixed Cu/Zn sites cannot be excluded. The intermetallic Cu center dot center dot center dot Co and Co center dot center dot center dot Zn distances are 2.924 (3) and 2.906 (3) angstrom, respectively. The neutral molecules are held together by N-H center dot center dot center dot O hydrogen bonds involving amine groups from the 2,2'-iminodiethanol ligands and acetate groups to build two-dimensional layers.

AB - The crystal structure of the title compound, triacetato-1 kappa O;3 kappa O-4,O'-(2,2'-iminodiethanol)-1 kappa O-3,N,O'bis(mu-2,2'-iminodiethanolato)1 kappa O-2: 2 kappa O-6,N,O':3 kappa O-2'-cobalt(III)copper(II)-zinc(II), [CoCuZn(C4H9NO2)(2)(C2H3O2)(3)(C4H11NO2)], shows a molecule with a triangular three-metal core. The metal sites were refined with full occupancies, but the possibility that the Zn and Cu positions are actually mixed Cu/Zn sites cannot be excluded. The intermetallic Cu center dot center dot center dot Co and Co center dot center dot center dot Zn distances are 2.924 (3) and 2.906 (3) angstrom, respectively. The neutral molecules are held together by N-H center dot center dot center dot O hydrogen bonds involving amine groups from the 2,2'-iminodiethanol ligands and acetate groups to build two-dimensional layers.

U2 - 10.1107/S010827010601523X

DO - 10.1107/S010827010601523X

M3 - Article

VL - 62

SP - m246-m248

JO - Acta Crystallographica Section C: Structural Chemistry

JF - Acta Crystallographica Section C: Structural Chemistry

SN - 1600-5759

IS - 6

ER -