A gem-organodizinc species assembled in a tetrameric cage

P.C. Andrews; C.L. Raston; Brian Skelton; Allan White

doi:10.1021/om970986u

A gem-organodizinc species assembled in a tetrameric cage

P.C. Andrews, C.L. Raston, Brian Skelton, Allan White

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Abstract

Treatment of both polymeric [{(2-pyridyl)-(SiMe3)C}SbCl](infinity) and the implied stibene (Sb=C) containing red oil, formed as a result of Me3SiCl elimination from [{(2-pyridyl)(SiMe3)(2)C}(2)SbCl], with excess Et2Zn in the presence of tmeda results in the geminal organodizinc chiral cage tetramer [Zn{C(SiMe3)(2-pyridyl)}](4) possessing three-coordinate metal centers, [(tmeda)Et-(Cl)Zn] and [(tmeda)Et2Zn].

Original language	English
Pages (from-to)	779-782
Journal	Organometallics
Volume	17
Issue number	N/A
DOIs	https://doi.org/10.1021/om970986u
Publication status	Published - 1998

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abstract = "Treatment of both polymeric [{(2-pyridyl)-(SiMe3)C}SbCl](infinity) and the implied stibene (Sb=C) containing red oil, formed as a result of Me3SiCl elimination from [{(2-pyridyl)(SiMe3)(2)C}(2)SbCl], with excess Et2Zn in the presence of tmeda results in the geminal organodizinc chiral cage tetramer [Zn{C(SiMe3)(2-pyridyl)}](4) possessing three-coordinate metal centers, [(tmeda)Et-(Cl)Zn] and [(tmeda)Et2Zn].",

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doi = "10.1021/om970986u",

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T1 - A gem-organodizinc species assembled in a tetrameric cage

AU - Andrews, P.C.

AU - Raston, C.L.

AU - Skelton, Brian

AU - White, Allan

PY - 1998

Y1 - 1998

N2 - Treatment of both polymeric [{(2-pyridyl)-(SiMe3)C}SbCl](infinity) and the implied stibene (Sb=C) containing red oil, formed as a result of Me3SiCl elimination from [{(2-pyridyl)(SiMe3)(2)C}(2)SbCl], with excess Et2Zn in the presence of tmeda results in the geminal organodizinc chiral cage tetramer [Zn{C(SiMe3)(2-pyridyl)}](4) possessing three-coordinate metal centers, [(tmeda)Et-(Cl)Zn] and [(tmeda)Et2Zn].

AB - Treatment of both polymeric [{(2-pyridyl)-(SiMe3)C}SbCl](infinity) and the implied stibene (Sb=C) containing red oil, formed as a result of Me3SiCl elimination from [{(2-pyridyl)(SiMe3)(2)C}(2)SbCl], with excess Et2Zn in the presence of tmeda results in the geminal organodizinc chiral cage tetramer [Zn{C(SiMe3)(2-pyridyl)}](4) possessing three-coordinate metal centers, [(tmeda)Et-(Cl)Zn] and [(tmeda)Et2Zn].

U2 - 10.1021/om970986u

DO - 10.1021/om970986u

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JO - Organometallics

JF - Organometallics

IS - N/A

ER -

A gem-organodizinc species assembled in a tetrameric cage

Abstract

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