A gem-aluminium(III)/antimony(III) C centre incorporated in a bimetallic six-membered heterocycle

P.C. Andrews; C.L. Raston; Brian Skelton; Allan White

doi:10.1039/a700959c

A gem-aluminium(III)/antimony(III) C centre incorporated in a bimetallic six-membered heterocycle

P.C. Andrews, C.L. Raston, Brian Skelton, Allan White

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Reaction of AlMe3 with the implied stibene intermediate (Sb=C drop) form ed in the reaction of [(2-pyr)(SiMe3)(2)CLi . tmeda] with SbCl3 affords the carboalumination product containing a gem-Al/Sb C centre as part of a six-membered heterocycle, [(2-pyr)(SiMe3)(2)C-Sb(Me)-(2-pyr)(SiMe3)C-Al(Me)(2)] 1, structurally authenticated as the (RS,SR) diastereoisomer.

Original language	English
Pages (from-to)	1183-1184
Journal	Chemical Communications
Volume	N/A
DOIs	https://doi.org/10.1039/a700959c
Publication status	Published - 1997

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abstract = "Reaction of AlMe3 with the implied stibene intermediate (Sb=C drop) form ed in the reaction of [(2-pyr)(SiMe3)(2)CLi . tmeda] with SbCl3 affords the carboalumination product containing a gem-Al/Sb C centre as part of a six-membered heterocycle, [(2-pyr)(SiMe3)(2)C-Sb(Me)-(2-pyr)(SiMe3)C-Al(Me)(2)] 1, structurally authenticated as the (RS,SR) diastereoisomer.",

author = "P.C. Andrews and C.L. Raston and Brian Skelton and Allan White",

year = "1997",

doi = "10.1039/a700959c",

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pages = "1183--1184",

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T1 - A gem-aluminium(III)/antimony(III) C centre incorporated in a bimetallic six-membered heterocycle

AU - Andrews, P.C.

AU - Raston, C.L.

AU - Skelton, Brian

AU - White, Allan

PY - 1997

Y1 - 1997

N2 - Reaction of AlMe3 with the implied stibene intermediate (Sb=C drop) form ed in the reaction of [(2-pyr)(SiMe3)(2)CLi . tmeda] with SbCl3 affords the carboalumination product containing a gem-Al/Sb C centre as part of a six-membered heterocycle, [(2-pyr)(SiMe3)(2)C-Sb(Me)-(2-pyr)(SiMe3)C-Al(Me)(2)] 1, structurally authenticated as the (RS,SR) diastereoisomer.

AB - Reaction of AlMe3 with the implied stibene intermediate (Sb=C drop) form ed in the reaction of [(2-pyr)(SiMe3)(2)CLi . tmeda] with SbCl3 affords the carboalumination product containing a gem-Al/Sb C centre as part of a six-membered heterocycle, [(2-pyr)(SiMe3)(2)C-Sb(Me)-(2-pyr)(SiMe3)C-Al(Me)(2)] 1, structurally authenticated as the (RS,SR) diastereoisomer.

UR - https://www.scopus.com/pages/publications/0002269749

U2 - 10.1039/a700959c

DO - 10.1039/a700959c

M3 - Article

VL - N/A

SP - 1183

EP - 1184

JO - Chemical Communications

JF - Chemical Communications

ER -

A gem-aluminium(III)/antimony(III) C centre incorporated in a bimetallic six-membered heterocycle

Abstract

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