[7,8-bis-(di-phenyl-phosphino)-7,8-dicarba-nido-undeca-borato- κ2 P,P′]gold(I)-dichloro-methane-water (2/1/1)

Joseph A. Ioppolo, Jack K. Clegg, Louis M. Rendina

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The title compound, [Au(C26H30B10P2)(C26H30B9P2)]·0. 5CH2Cl2·0.5H2O, contains two independent complex mol-ecules in the asymmetric unit. The gold(I) centres display a distorted tetra-hedral geometry. The complex is stablized through weak intra-molecular π-π stacking (Cg⋯Cg = 4.17 Å) and edge-to-face inter-actions (H⋯Cg = 3.21 Å). Adjacent mol-ecules inter-act through C - H⋯π (H⋯Cg = 2.88 Å) and B - H⋯π (H⋯Cg = 3.15 Å) contacts, forming a three-dimensional network, with solvent mol-ecules occupying the cavities. One of the phenyl groups was disordered over two sites with occupancy factors of 0.65 and 0.35.

Original languageEnglish
Pages (from-to)m603-m604
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number5
DOIs
Publication statusPublished - 2009
Externally publishedYes

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