2 : 1 Ba/Ti(IV) Heterobimetallic complex based on two calix[6]arenes

A.J. Petrella, N.K. Roberts, D.C. Craig, Colin Raston, R.N. Lamb

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Abstract

Reaction of p-Bu-t-calix[6]arene with barium metal in methanol then [Ti(OPri)(4)] affords a heterobimetallic complex with a central Ti(IV) attached to two calix[6]arenes in the 1,3-alternate conformation, each with an endo-barium sharing common phenolate groups with the titanium centre.
Original languageEnglish
Pages (from-to)2288-2289
JournalChemical Communications
Volume18
DOIs
Publication statusPublished - 2003

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Petrella, A. J., Roberts, N. K., Craig, D. C., Raston, C., & Lamb, R. N. (2003). 2 : 1 Ba/Ti(IV) Heterobimetallic complex based on two calix[6]arenes. Chemical Communications, 18, 2288-2289. https://doi.org/10.1039/b302346j