11-Hydroxy-3,3-dimethyl-7,12-dioxo-3,4,6,6a,7,12,12a,12b-octahydrobenz[a]anthracen-1-yl acetate

T. Rozek, J.H. Bowie, Brian Skelton, Allan White

Research output: Contribution to journalArticle

Abstract

The Diels-Alder reaction between 5-hydroxy-1,4-naphthoquinone and 5,5-dimethyl-3-vinyl-1,2-cyclohexadienyl acetate by endo addition gives the title compound, C22H22O5, in 68% yield. This racemic diastereoisomer has the opposite regiochemistry to ochromycinone analogues produced previously and may allow access to a new type of anticancer-active saquayamycin analogue.
Original languageEnglish
Pages (from-to)o431-o432
JournalActa Crystallographica Section C - Crystal Structure Communications
Volume59
Issue number8
DOIs
Publication statusPublished - 2003

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