Alexandre Sobolev

Dr

  • The University of Western Australia (M310), 35 Stirling Highway, Room 450, Bayliss Building, Perth campus

    6009 Perth

    Australia

  • 2294 Citations
  • 26 h-Index
19942019
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Research Output 1994 2019

  • 2294 Citations
  • 26 h-Index
  • 170 Article
  • 3 Review article
  • 2 Conference paper
  • 1 Conference article
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Article
2019
Rhodium
Metals
Polymerization
Derivatives
Atoms

Allan White and Polypyridines: Extending the Lanthanide(iii) Complex Series

Cotton, S. A., Harrowfield, J. M., Semenova, L. I., Skelton, B. W., Sobolev, A. N. & White, A. H., 21 Jun 2019, In : Australian Journal of Chemistry.

Research output: Contribution to journalArticle

Lanthanoid Series Elements
Ligands
Bromides
Crystal lattices
Metals
2 Citations (Scopus)

Allan White and Solvento/Aqua Complexes: ScIII Solvation

Chan, E. J., Cotton, S. A., Harrowfield, J. M., Skelton, B. W., Sobolev, A. N. & White, A. H., 4 Jul 2019, In : Australian Journal of Chemistry.

Research output: Contribution to journalArticle

Solvation
Ligands
Picrates
Scandium
Anions
1 Citation (Scopus)

A spectroscopic and computationally minimal approach to the analysis of charge-transfer processes in conformationally fluxional mixed-valence and heterobimetallic complexes

Gückel, S., Gluyas, J. B. G., Eaves, S. G., Safari, P., Yufit, D. S., Sobolev, A. N., Kaupp, M. & Low, P. J., 2 Jul 2019, In : Chemistry - A European Journal. 25, 37, p. 8837-8853

Research output: Contribution to journalArticle

Discrete Fourier transforms
Charge transfer
Molecular electronics
Geometry
Potential energy
1 Downloads (Pure)

Carbon-Rich Trinuclear Octamethylferrocenophanes

Roemer, M., Wild, D. A., Sobolev, A. N., Skelton, B. W., Nealon, G. L., Piggott, M. J. & Koutsantonis, G. A., 18 Mar 2019, In : Inorganic Chemistry. 56, 6, p. 3789–3799

Research output: Contribution to journalArticle

Carbon
Friedel-Craft reaction
Metals
Friedel-Crafts reaction
ferrocenes

Chemically and Mechanically Controlled Single-Molecule Switches Using Spiropyrans

Walkey, M. C., Peiris, C. R., Ciampi, S., C. Aragonès, A., Domínguez-Espíndola, R. B., Jago, D., Pulbrook, T., Skelton, B. W., Sobolev, A. N., Díez Pérez, I., Piggott, M. J., Koutsantonis, G. A. & Darwish, N., 9 Oct 2019, In : ACS APPLIED MATERIALS & INTERFACES. 11, 40, p. 36886-36894 9 p.

Research output: Contribution to journalArticle

Crystal structures of an imidazo[1,5-a]pyridinium-based ligand and its (C13H12N3)(2)[CdI4] hybrid salt

Vassilyeva, O. Y., Buvaylo, E. A., Kokozay, V. N., Skelton, B. W. & Sobolev, A. N., Aug 2019, In : Acta Crystallographica. Section E: Structure Reports Online. 75, p. 1209-+ 23 p.

Research output: Contribution to journalArticle

Open Access

Investigation of an Unusual Crystal Habit of Hydrochlorothiazide Reveals Large Polar Enantiopure Domains and a Possible Crystal Nucleation Mechanism

Thomas, S. P., Grosjean, A., Flematti, G. R., Karton, A., Sobolev, A. N., Edwards, A. J., Piltz, R. O., Iversen, B. B., Koutsantonis, G. A. & Spackman, M. A., 22 Jul 2019, In : Angewandte Chemie - International Edition. 58, 30, p. 10255-10259 5 p.

Research output: Contribution to journalArticle

Hydrochlorothiazide
Habits
Nucleation
Crystals
Observation

Photophysical and biological investigation of phenol substituted rhenium tetrazolato complexes

Akabar, N., Chaturvedi, V., Shillito, G. E., Schwehr, B. J., Gordon, K. C., Huff, G. S., Sutton, J. J., Skelton, B. W., Sobolev, A. N., Stagni, S., Nelson, D. J. & Massi, M., 1 Jan 2019, In : Dalton Transactions. 48, 41, p. 15613-15624 12 p.

Research output: Contribution to journalArticle

Rhenium
Phenol
Excited states
Phosphorescence
Deprotonation

Photophysical investigation of near infrared emitting lanthanoid complexes incorporating tris(2-naphthoyl)methane as a new antenna ligand

Abad Galán, L., Wada, S., Cameron, L., Sobolev, A. N., Hasegawa, Y., Zysman-Colman, E., Ogden, M. I. & Massi, M., 1 Jan 2019, In : Dalton Transactions. 48, 11, p. 3768-3776 9 p.

Research output: Contribution to journalArticle

Lanthanoid Series Elements
Methane
Quantum yield
Dimethyl Sulfoxide
Antennas

Racemic NHC-Iridium Complexes with Electron-Poor Diene Ligands and Their Reactivity in the Intramolecular Hydroamination Reaction

Gao, P., Foster, D., Sipos, G., Skelton, B. W., Sobolev, A. N., Moggach, S. A. & Dorta, R., 5 Sep 2019, In : Organometallics. 38, 19, p. 3568-3581

Research output: Contribution to journalArticle

Iridium
dienes
iridium
reactivity
Ligands
1 Citation (Scopus)

Rhodium(I)-α-Phenylvinylfluorenyl Complexes: Synthesis, Characterization, and Evaluation as Initiators in the Stereospecific Polymerization of Phenylacetylene

Tan, N. S. L., Simpson, P. V., Nealon, G. L., Sobolev, A. N., Raiteri, P., Massi, M., Ogden, M. I. & Lowe, A. B., 7 Feb 2019, In : European Journal of Inorganic Chemistry. 2019, 5, p. 592-601 10 p.

Research output: Contribution to journalArticle

Rhodium
phosphine
Polymerization
Fluorine
X ray analysis
2 Citations (Scopus)

Structural Systematics of Lanthanide(iii) Picrate Solvates: Neutral, Mononuclear Ln(pic)3(dimethylsulfoxide)3 Arrays

Asfari, Z., Chan, E. J., Harrowfield, J. M., Skelton, B. W., Sobolev, A. N., Thuéry, P. & White, A. H., 17 Jun 2019, In : Australian Journal of Chemistry.

Research output: Contribution to journalArticle

Lanthanoid Series Elements
Dimethyl Sulfoxide
Atoms
Ligands
Stoichiometry
Hempa
Lanthanoid Series Elements
Stoichiometry
Ligands
Picrates
2 Citations (Scopus)

Structural Systematics of Lanthanide(iii) Picrate Solvates: Molecular, Mononuclear Ln(pic)3(trimethylphosphate)3 Arrays

Chan, E. J., Harrowfield, J. M., Skelton, B. W., Sobolev, A. N. & White, A. H., 3 Jul 2019, In : Australian Journal of Chemistry.

Research output: Contribution to journalArticle

Lanthanoid Series Elements
Stereochemistry
Ligands
Isomers
Atoms
1 Citation (Scopus)
1-methyl-2-pyrrolidinone
Lanthanoid Series Elements
Hempa
Ligands
Dimethyl Sulfoxide
1 Citation (Scopus)
1-methyl-2-pyrrolidinone
Europium
Stereochemistry
Dimethyl Sulfoxide
Hempa

Total synthesis of the antimalarial ascidian natural product albopunctatone

Pullella, G. A., Wdowiak, A. P., Sykes, M. L., Lucantoni, L., Sukhoverkov, K. V., Zulfiqar, B., Sobolev, A. N., West, N. P., Mylne, J. S., Avery, V. M. & Piggott, M. J., 9 Jul 2019, In : Organic Letters. 21, 14, p. 5519-5523 5 p.

Research output: Contribution to journalArticle

Urochordata
anthraquinones
Antimalarials
Biological Products
Anthraquinones

Turning the Tap: Conformational Control of Quantum Interference to Modulate Single-Molecule Conductance

Jiang, F., Trupp, D. I., Algethami, N., Zheng, H., He, W., Alqorashi, A., Zhu, C., Tang, C., Li, R., Liu, J., Sadeghi, H., Shi, J., Davidson, R., Korb, M., Sobolev, A. N., Naher, M., Sangtarash, S., Low, P. J., Hong, W. & Lambert, C. J., 15 Oct 2019, In : Angewandte Chemie - International Edition.

Research output: Contribution to journalArticle

Quantum interference phenomena
Molecules
Oligomers
Conformations
Charge transfer
2018
10 Downloads (Pure)
Open Access
File
Boronic Acids
Addition reactions
Rhodium
Tuning
Ligands
6 Citations (Scopus)

Energy transfer between Eu3+ and Nd3+ in near-infrared emitting beta-triketonate coordination polymers

Galan, L. A., Sobolev, A. N., Skelton, B. W., Zysman-Colman, E., Ogden, M. I. & Massi, M., 21 Sep 2018, In : Dalton Transactions. 47, 35, p. 12345-12352 8 p.

Research output: Contribution to journalArticle

Open Access

Exploring structural and conformational behaviour of cyclophanes incorporating imidazole-2-thiones

Mageed, A. H., Skelton, B. W., Sobolev, A. N. & Baker, M. V., 14 Jun 2018, In : Tetrahedron. 74, 24, p. 2956-2966 11 p.

Research output: Contribution to journalArticle

Thiones
Conformations
Sulfur
X-Ray Diffraction
Magnetic Resonance Spectroscopy

Facile Synthesis of Pentamethylcyclopentadienyl Ruthenium Half-Sandwich Complexes by Naphthalene Displacement

Stone, J., Jago, D., Sobolev, A., Spackman, M. & Koutsantonis, G., 27 Mar 2018, In : Australian Journal of Chemistry. 71, 4, p. 289-294 6 p.

Research output: Contribution to journalArticle

Ruthenium
Methane
Organometallics
Single crystals
X rays
2 Citations (Scopus)
Ligands
Oxidation
Cations
Nuclear magnetic resonance
Nuclear magnetic resonance spectroscopy
12 Citations (Scopus)
43 Downloads (Pure)

Iron versus Ruthenium: Clarifying the Electronic Differences between Prototypical Mixed-Valence Organometallic Butadiyndiyl Bridged Molecular Wires

Gueckel, S., Gluyas, J. B. G., El-Tarhuni, S., Sobolev, A. N., Whiteley, M. W., Halet, J-F., Lapinte, C., Kaupp, M. & Low, P. J., 14 May 2018, In : Organometallics. 37, 9, p. 1432-1445 14 p.

Research output: Contribution to journalArticle

Open Access
File
2 Citations (Scopus)

Lanthanoid complexes supported by retro-Claisen condensation products of -triketonates

Galan, L. A., Sobolev, A. N., Zysman-Colman, E., Ogden, M. I. & Massi, M., 28 Dec 2018, In : Dalton Transactions. 47, 48, p. 17469-17478 10 p.

Research output: Contribution to journalArticle

2 Citations (Scopus)

Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array

Ling, I., Kumari, H., Mirzamani, M., Sobolev, A. N., Garvey, C. J., Atwood, J. L. & Raston, C. L., 4 Oct 2018, In : Chemical Communications. 54, 77, p. 10824-10827 4 p.

Research output: Contribution to journalArticle

Yttrium
Dissolution
Compaction
Ions
Molecules
4 Citations (Scopus)

Probing the effect of beta-triketonates in visible and NIR emitting lanthanoid complexes

Galan, L. A., Reid, B. L., Stagni, S., Sobolev, A. N., Skelton, B. W., Moore, E. G., Hanan, G. S., Zysman-Colman, E., Ogden, M. I. & Massi, M., 28 Jun 2018, In : Dalton Transactions. 47, 24, p. 7956-7964 9 p.

Research output: Contribution to journalArticle

2017
2 Citations (Scopus)
129 Downloads (Pure)

Approaching an experimental electron density model of the biologically active trans-epoxysuccinyl amide group—Substituent effects vs. crystal packing

Shi, M. W., Stewart, S. G., Sobolev, A. N., Dittrich, B., Schirmeister, T., Luger, P., Hesse, M., Chen, Y. S., Spackman, P. R., Spackman, M. A. & Grabowsky, S., 1 Nov 2017, In : Journal of Physical Organic Chemistry. 30, 11, p. 1-15 15 p., e3683.

Research output: Contribution to journalArticle

Open Access
File
Amides
amides
Carrier concentration
Crystals
activity (biology)
1 Citation (Scopus)

Chiral discrimination in solid-state interactions of cobalt(III)-polyamine complex cations with tris-(dipicolinato)lanthanate(III) anions

Harrowfield, J. M., Kim, Y., Skelton, B. W., Sobolev, A. N. & White, A. H., 7 May 2017, In : CrystEngComm. 19, 17, p. 2372-2379 8 p.

Research output: Contribution to journalArticle

1 Citation (Scopus)
64 Downloads (Pure)
Open Access
File
Sodium Hydroxide
Cyclization
Discrete Fourier transforms
Electrons
9 Citations (Scopus)
134 Downloads (Pure)

In-Depth Study on Chloride Abstractions from (NHC)Ir(COD)CI Complexes

Sipos, G., Gao, P., Foster, D., Skelton, B. W., Sobolev, A. N. & Dorta, R., 27 Feb 2017, In : Organometallics. 36, 4, p. 801-817 17 p.

Research output: Contribution to journalArticle

Open Access
File
8 Citations (Scopus)

Insulated molecular wires: Inhibiting orthogonal contacts in metal complex based molecular junctions

Al-Owaedi, O. A., Bock, S., Milan, D. C., Oerthel, M. C., Inkpen, M. S., Yufit, D. S., Sobolev, A. N., Long, N. J., Albrecht, T., Higgins, S. J., Bryce, M. R., Nichols, R. J., Lambert, C. J. & Low, P. J., 28 Jul 2017, In : Nanoscale. 9, 28, p. 9902-9912 11 p.

Research output: Contribution to journalArticle

Open Access
Coordination Complexes
Scanning tunneling microscopy
Metal complexes
Platinum
Ligands
2 Citations (Scopus)
134 Downloads (Pure)

New, potentially chelating NHC ligands; synthesis, complexation studies, and preliminary catalytic evaluation

Ou, A., Wu, L., Salvador, A., Sipos, G., Zhao, G., Skelton, B. W., Sobolev, A. N. & Dorta, R., 21 Mar 2017, In : Dalton Transactions. 46, 11, p. 3631-3641 11 p.

Research output: Contribution to journalArticle

Open Access
File
Chelation
Complexation
Ligands
Iridium
Ruthenium

Stereoelectronic Effects on Dienophile Separation Influence the Diels–Alder Synthesis of Molecular Clefts

Stoermer, M. J., Wickramasinghe, W. A., Byriel, K. A., Hockless, D. C. R., Skelton, B. W., Sobolev, A. N., White, A. H., Mak, J. Y. W. & Fairlie, D. P., 8 Dec 2017, In : European Journal of Organic Chemistry. 2017, 45, p. 6793-6796 4 p.

Research output: Contribution to journalArticle

Alkenes
alkenes
Cycloaddition
cycloaddition
synthesis
4 Citations (Scopus)
Lanthanoid Series Elements
Anions
Cations
Hydrates
10 Citations (Scopus)

Visible and Near-Infrared Emission from Lanthanoid beta-Triketonate Assemblies Incorporating Cesium Cations

Galan, L. A., Reid, B. L., Stagni, S., Sobolev, A. N., Skelton, B. W., Cocchi, M., Malicka, J. M., Zysman-Colman, E., Moore, E. G., Ogden, M. I. & Massi, M., 7 Aug 2017, In : Inorganic Chemistry: including bioinorganic chemistry. 56, 15, p. 8975-8985 11 p.

Research output: Contribution to journalArticle

Open Access
2016

Deprotonation of Large Calixarenes-Cation Binding and Conformations

Harrowfield, J. M., Koutsantonis, G. A., Ogden, M. I., Sobolev, A. N. & White, A. H., 2016, In : Australian Journal of Chemistry. 69, 5, p. 546-554 9 p.

Research output: Contribution to journalArticle

Calixarenes
Deprotonation
Conformations
Cations
Anions

Functional heterocyclic molecular inclusion in: P -sulfonatocalix[5]arene and lanthanide(III) complexes

Ling, I., Sobolev, A. N. & Raston, C. L., 28 Oct 2016, In : RSC Advances. 6, 104, p. 102695-102702 8 p.

Research output: Contribution to journalArticle

Lanthanoid Series Elements
Calixarenes
Rare earth elements
Molecules
Conformations
1 Citation (Scopus)

Gadolinium(III)-mediated multi-component confinement of imidazolium cations in: P-sulfonated calix[4]arene

Ling, I., Sobolev, A. & Raston, C. L., Jul 2016, In : CrystEngComm. 18, 26, p. 4929-4937

Research output: Contribution to journalArticle

Calixarenes
Gadolinium
capsules
gadolinium
Capsules
1 Citation (Scopus)

Investigation of the structure and magnetism in lanthanide β-triketonate tetranuclear assemblies

Reid, B. L., Woodward, R. C., Fuller, R. O., Sobolev, A. N., Skelton, B. W., Ogden, M. I. & Massi, M., 5 May 2016, In : Journal of Coordination Chemistry. 69, 11-13, p. 1852-1863

Research output: Contribution to journalArticle

Lanthanoid Series Elements
Magnetism
Rare earth elements
alkali metals
assemblies
3 Citations (Scopus)

Lanthanoid Complexation by a Tris-Tetrazole-Functionalised Calix[4]arene

D'Alessio, D., Skelton, B. W., Sobolev, A. N., Krause-Heuer, A. M., Fraser, B. H., Massi, M. & Ogden, M. I., Dec 2016, In : European Journal of Inorganic Chemistry. 2016, 34, p. 5366-5372

Research output: Contribution to journalArticle

Lanthanoid Series Elements
Calixarenes
Complexation
Buffers
Praseodymium
2 Citations (Scopus)

Syntheses and structures of some complexes containing M3(µ-dppm)3 moieties (M = Cu, Ag) linking C4{M'Lx} groups [M'Lx = Re(CO)3(But2-bpy), Ru(dppe)Cp*]

Bruce, M. I., Ellis, B. G., Halet, J. F., Le Guennic, B., Nicholson, B. K., Sahnoune, H., Scoleri, N., Skelton, B. W., Sobolev, A. N., Sumby, C. J., White, A. H. & Zaitseva, N. N., 1 Nov 2016, In : Inorganica Chimica Acta. 453, p. 654-666

Research output: Contribution to journalArticle

Carbon Monoxide
Acetone
acetone
synthesis
Polymorphism
2015
14 Citations (Scopus)
115 Downloads (Pure)

Broad-Band NIR Transient Absorption Spectroscopy of an "All-Carbon"-Bridged Bimetallic Radical Cation Complex

Gluyas, J., Sobolev, A., Moore, E. G. & Low, P., 5 Aug 2015, In : Organometallics. 34, 16, p. 3923-3926

Research output: Contribution to journalArticle

Open Access
File
Absorption spectroscopy
Cations
Absorption spectra
absorption spectroscopy
Carbon
7 Citations (Scopus)

Controlling the organization of phosphonium cations relative to p-sulfonatocalix[4]arene anions

Ling, I., Sobolev, A. & Raston, C. L., Feb 2015, In : CrystEngComm. 17, 7, p. 1526-1530

Research output: Contribution to journalArticle

Calixarenes
Anions
Cations
Negative ions
Positive ions
5 Citations (Scopus)

Efficient packing of long flexible bis-imidazolium cations in the ubiquitous bilayers of their p-sulfonatocalixarene salts

Ling, I., Sobolev, A., Sabah, K. & Hashim, R., 14 Aug 2015, In : CrystEngComm. 17, 30, p. 5841-5848

Research output: Contribution to journalArticle

Calixarenes
Lanthanoid Series Elements
Rare earth elements
Cations
Salts
5 Citations (Scopus)
136 Downloads (Pure)

Electrostatic complementarity in pseudoreceptor modeling based on drug molecule crystal structures: The case of loxistatin acid (E64c)

Shi, M., Sobolev, A., Schirmeister, T., Engels, B., Schmidt, T. C., Luger, P., Mebs, S., Dittrich, B., Chen, Y., Bąk, J., Jayatilaka, D., Bond, C., Turner, M., Stewart, S., Spackman, M. & Grabowsky, S., 1 Mar 2015, In : New Journal of Chemistry. 39, 3, p. 1628-1633 6 p.

Research output: Contribution to journalArticle

Open Access
File
Electrostatics
Crystal structure
Cysteine Proteinase Inhibitors
Molecules
Acids
12 Citations (Scopus)

Lanthanoid/Alkali Metal β-Triketonate Assemblies: A Robust Platform for Efficient NIR Emitters

Reid, B. L., Stagni, S., Malicka, J. M., Cocchi, M., Sobolev, A., Skelton, B., Moore, E. G., Hanan, G. S., Ogden, M. I. & Massi, M., 7 Dec 2015, In : CHEMISTRY-A EUROPEAN JOURNAL. 21, 50, p. 18354–18363 10 p.

Research output: Contribution to journalArticle

Alkali Metals
Lanthanoid Series Elements
Infrared radiation
Ligands
Solvation
9 Citations (Scopus)

Vinyl sulfone building blocks in covalently reversible reactions with thiols

Schneider, T. H., Rieger, M., Ansorg, K., Sobolev, A., Schirmeister, T., Engels, B. & Grabowsky, S., 1 Jul 2015, In : New Journal of Chemistry. 39, 7, p. 5841-5853

Research output: Contribution to journalArticle

Open Access
Sulfhydryl Compounds
Nucleophiles
Electrostatics
Mirrors
Substitution reactions